Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 9: Issue 1
Kinetics of the thermal decomposition of ammonium thiocarbamate
Authors:
V. Djakovitch Department of Inorganic Chemistry University of Sofia 1 Anton Ivanov Ave. Sofia Bulgaria

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T. Romanowska Institute of Chemistry Jagellonian University 30 060 Cracow Poland

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Pages:
9–21
Online Publication Date:
13 Aug 2005
Publication Date:
01 Feb 1976
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01909259
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Results of the kinetic study of the thermal decomposition of ammonium thiocarbamate in vacuum (ca. 10−2 torr) in the temperature range 303–353 K are presented. Under these conditions ammonium thiocarbamate decomposes into gaseous products (NH4COSNH2→2 NH3 + COS). Fifteen general equations for the kinetics of thermal decomposition of solids were taken into consideration. The following equation describes the experimental results over the whole range of the degree of decomposition:
\documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{upgreek} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} $$\alpha = \frac{{2k_2 }}{{ab}}(t - t_0 )[a + b - 2k_2 (t - t_0 )]$$ \end{document}
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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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