Authors:
Marie-Noelle Avettand-Fènoël U.M.R. C.N.R.S. 8517, Université de Lille 1 Laboratoire de Métallurgie Physique et Génie des Matériaux 59650 Villeneuve D’Ascq France

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N. David U.M.R. C.N.R.S. 7555, Université Henri Poincaré, Nancy I Laboratoire de Chimie du Solide Minéral 54506 Vandoeuvre Les Nancy France

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G. Reumont U.M.R. C.N.R.S. 8517, Université de Lille 1 Laboratoire de Métallurgie Physique et Génie des Matériaux 59650 Villeneuve D’Ascq France

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J. Fiorani U.M.R. C.N.R.S. 7555, Université Henri Poincaré, Nancy I Laboratoire de Chimie du Solide Minéral 54506 Vandoeuvre Les Nancy France

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M. Vilasi U.M.R. C.N.R.S. 7555, Université Henri Poincaré, Nancy I Laboratoire de Chimie du Solide Minéral 54506 Vandoeuvre Les Nancy France

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P. Perrot U.M.R. C.N.R.S. 8517, Université de Lille 1 Laboratoire de Métallurgie Physique et Génie des Matériaux 59650 Villeneuve D’Ascq France

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Abstract  

The Fe-Sn-Zn system is of interest because Sn is one element added to the Zn galvanizing bath to overcome the drawbacks due to the presence of Si in semi-killed steels. This work has been undertaken with the aim to understand the tin effect on the microstructure and the layers growth in batch galvanized coatings on low alloyed steels. Various experimental techniques such as metallography, scanning electron microscopy (SEM) coupled with X-ray energy dispersive spectroscopy (EDX) are used in order to characterize the microstructure and the properties of such coatings elaborated in a zinc bath enriched with tin. Solidification phenomena and layers growth mechanisms during galvanization are explained by means of the ternary phase diagram Fe-Sn-Zn at 450�C. The Calphad method allows to obtain this phase diagram from the three optimized binary phase diagrams Fe-Sn, Fe-Zn and Sn-Zn and some experimental data inside the ternary Fe-Sn-Zn system.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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