Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 90: Issue 2
Thermodynamic assessment of the Ag-Au-Bi and Ag-Au-Sb systems
Authors:
E. Zoro UMR 8182, ICMMO, Université de Paris-Sud XI Laboratoire de Physicochimie de l’Etat Solide 91405 Orsay Cedex France

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C. Servant UMR 8182, ICMMO, Université de Paris-Sud XI Laboratoire de Physicochimie de l’Etat Solide 91405 Orsay Cedex France

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B. Legendre Université de Paris-Sud XI Laboratoire de Chimie-Physique Minérale et Bioinorganique de la Faculté de Pharmacie de Châtenay-Malabry, EA 401 Orsay Cedex France

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Pages:
347–353
Online Publication Date:
07 Dec 2007
Publication Date:
01 Nov 2007
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-007-8392-1
Keywords:
Ag-Au-Bi system; Ag-Au-Sb system; calphad method; enthalpy of formation; EPMA; heat flow calorimeter; phase diagram; solder; XRD
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Abstract  

The aim of the action of COST 531 taking into account the eleven elements Ag,Au,Bi,Cu,In,Pb,Sb,Sn,Zr (solder), Ni and Pd (substrate) is the database assessment for candidates of lead free soldering process. We studied four of them forming the ternary systems Ag-Au-Bi and Ag-Au-Sb. First we determined experimentally their phase diagrams, then the integral enthalpy of mixing of the liquid phase along different sections at different temperatures by using a SETARAM device heat flow calorimeter of Tian-Calvet type. All these data were used to optimize the thermodynamic parameters of the different phases of both ternary systems.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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