Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 90: Issue 2
The stability of inclusion compounds under heating
Part I. Inclusion compounds of microporous manganese formate with included dioxane {Mn(HCOO)2·1/3C4H8O2} and tetrahydrofurane {Mn(HCOO)2·1/3C4H8O}
Authors:
V. Logvinenko Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 Novosibirsk-90 630090 Russia

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D. Dybtsev Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 Novosibirsk-90 630090 Russia

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V. Fedin Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 Novosibirsk-90 630090 Russia

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V. Drebushchak Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 Novosibirsk-90 630090 Russia

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M. Yutkin Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 Novosibirsk-90 630090 Russia

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Pages:
463–467
Online Publication Date:
29 Apr 2007
Publication Date:
01 Nov 2007
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-006-7683-2
Keywords:
coordination compounds; inclusion compounds; ‘model free’ kinetics
Restricted access

Abstract  

The thermal decomposition of two inclusion compounds Mn(HCOO)2·1/3C4H8O2 and Mn(HCOO)2·1/3C4H8O was studied in the inert atmosphere. The process of both dioxane, and tetrahydrofurane removal has two steps; the intermediate phase is unstable and kinetically hindered. Manganese formate is stable up to 330°C. Thermogravimetric data (obtained at different rates of linear heating) were processed with computer program (with ‘Model free’ approach). Kinetic parameters were calculated for the first decomposition step, and the process is described by equation of n-order reaction with autocatalysis.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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