Authors:
A. Mishra University of Delhi Department of Chemistry Delhi 110007 India

Search for other papers by A. Mishra in
Current site
Google Scholar
PubMed
Close
,
S. Mishra University of the Free State Department of Chemistry 9866 Free State South Africa

Search for other papers by S. Mishra in
Current site
Google Scholar
PubMed
Close
,
N. Manav University of Delhi Department of Chemistry Delhi 110007 India

Search for other papers by N. Manav in
Current site
Google Scholar
PubMed
Close
, and
N. Kaushik University of Delhi Department of Chemistry Delhi 110007 India

Search for other papers by N. Kaushik in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract  

Palladium(II) complexes of type [Pd(L)Cl2] [where L=2-aminopyridine-N-thiohydrazide (L1), (2-aminopyridine-N-thio)-1,3-propanediamine (L2), benzaldehyde 2-aminopyridine-N-thiohydrazone (L3) and salicylaldehyde-2-aminopyridine-N-thiohydrazone (L4)] have been synthesized. The thiohydrazide, thiodiamine and thiohydrazones can exist as thione-thiol tautomer and coordinate as a bidentate N-S ligand. The ligands found to act in bidentate fashion. The complexes have been characterized by elemental analysis, IR, mass, electronic, 1H NMR spectroscopic studies, and TG/DTA study. Antifungal studies of some complexes were also carried out. Various kinetic and thermodynamic parameters like order of reaction (n), activation energy (Ea), apparent activation entropy (S#) and heat of reaction (ΔH) have also been carried out for one complex.

  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Aug 2024 11 0 0
Sep 2024 14 0 0
Oct 2024 51 0 0
Nov 2024 3 0 0
Dec 2024 6 0 0
Jan 2025 9 0 0
Feb 2025 15 0 0