Authors:
M. Aksu Erciyes University Yozgat Faculty of Science and Literature, Department of Chemistry Yozgat Turkey

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S. Durmuş Abant Izzet Baysal University Faculty of Education Bolu Turkey

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M. Sari Gazi University Faculty of Education Beşevler Ankara Turkey

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K. Emregül Ankara University Science Faculty, Department of Chemistry Tando ğan 06100 Ankara Turkey

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I. Svoboda Strukturforschung, FB Materialwissenschaft TU-Darmstadt Petersenstrasse 23 64287 Darmstadt Germany

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H. Fuess Strukturforschung, FB Materialwissenschaft TU-Darmstadt Petersenstrasse 23 64287 Darmstadt Germany

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O. Atakol Ankara University Science Faculty, Department of Chemistry Tando ğan 06100 Ankara Turkey

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Abstract  

N,N′-bis(salicylidene)-1,3-propanediamine (LH2), N,N′-bis(salicylidene)-2,2′-dimethyl-1,3-propanediamine (LDMH2), N,N′-bis(salicylidene)-2-hydroxy-1,3-propanediamine (LOH3), N,N′-bis(2-hydroxyacetophenylidene)-1,3-propanediamine (LACH2) and N,N′-bis(2-hydroxyacetophenone)-2,2′-dimethyl-1,3-propanediamine (LACDMH2) were synthesized and reduced to their phenol-amine form in alcoholic media using NaBH4 (LHH2, LDMHH2, LOHHH2, LACHH2 and LACDMHH2). Heterodinuclear complexes were synthesized using Ni(II), Zn(II) and Cd(II) salts, according to the template method in DMF media. The complex structures were analyzed using elemental analysis, IR spectroscopy, and thermogravimetry. Suitable crystals of only one complex were obtained and its structure determined using X-ray diffraction, NiLACH�CdBr2�DMF2, space group orthorhombic, Pbca, a=20.249, b=14.881, c=20.565 � and Z=8. The heterodinuclear complexes were seen to be of [Ni�ligand�MX2�DMF2] structure (ligand=LH2−, LDMH2−, LOHH2−, LACH2−, LACDMH2−, M=ZnII, CdII, X=Br, I). Thermogravimetric analysis showed irreversible bond breakage of the coordinatively bonded DMF molecules followed by decomposition at this temperature.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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