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  • 1 Department of Physical and Chemical Methodologies for Engineering, University of Catania, V.le Andrea Doria 6, 95125 Catania, Italy
  • | 2 Department of Chemistry IFM, University of Turin, Via Pietro Giuria 9, 10125 Torino, Italy
  • | 3 Department of General and Applied Organic Chemistry, University of Turin, Via Pietro Giuria 7, 10125 Torino, Italy
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Abstract  

Molar heat capacities of twelve linear alkane-α,ω-diamides H2NOC-(CH2)(n-2)-CONH2, (n=2 to 12 and n=14) were measured by differential scanning calorimetry at T=183 to 323 K. Heat flow rate calibration of the Mettler DSC 30 calorimeter was carried out by using benzoic acid as reference material. The calibration was checked by determining the molar heat capacity of urea in the same temperature range as that of measurements. The molar heat capacities of alkane-α,ω-diamides increased in function of temperature and fitted into linear equations. Smoothed values of Cp,m at 298.15 K displayed a linear increase with the number of carbon atoms. The Cp,m contribution of CH2 group was (22.6±0.4) J K−1 mol−1, in agreement with our previous results concerning linear alkane-a,ω-diols and primary alkylamides as well as the literature data on various series of linear alkyl compounds.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)