Authors:
V. Causin Universitŕ di Padova Dipartimento di Scienze Chimiche via Marzolo 1 35131 Padova Italy

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Carla Marega Universitŕ di Padova Dipartimento di Scienze Chimiche via Marzolo 1 35131 Padova Italy

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Roberta Saini Universitŕ di Padova Dipartimento di Scienze Chimiche via Marzolo 1 35131 Padova Italy

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A. Marigo Universitŕ di Padova Dipartimento di Scienze Chimiche via Marzolo 1 35131 Padova Italy

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G. Ferrara Basell Poliolefine Italia SpA — Centro Ricerche ‘Giulio Natta’ P.le Donegani 12 44100 Ferrara Italy

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Abstract  

The effect of clay dispersion on the crystallization behavior of isotactic polypropylene (iPP)-based nanocomposites is reported. The Tm0 of the materials was calculated by the method proposed by Marand, the kinetics of crystallization was evaluated by the Avrami analysis and also the Hoffman-Lauritzen theory of crystallization regimes was applied. Montmorillonite was found to depress Tm0, to enhance the rate of crystallization and to ease the chain folding of macromolecules. These effects were magnified if clay was exfoliated, rather than intercalated.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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