Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 90: Issue 3
A comparative study of thermodynamic properties of binary mixtures containing dimethylsulfoxide
Authors:
B. Marongiu Università Degli Studi Cagliari, Cittadella Universitaria di Monserrato Dipartimento di Scienze Chimiche 09042 Cagliari Italy

Search for other papers by B. Marongiu in
Current site
Google Scholar
PubMed Close
,
Alessandra Piras Università Degli Studi Cagliari, Cittadella Universitaria di Monserrato Dipartimento di Scienze Chimiche 09042 Cagliari Italy

Search for other papers by Alessandra Piras in
Current site
Google Scholar
PubMed Close
,
Silvia Porcedda Università Degli Studi Cagliari, Cittadella Universitaria di Monserrato Dipartimento di Scienze Chimiche 09042 Cagliari Italy

Search for other papers by Silvia Porcedda in
Current site
Google Scholar
PubMed Close
, and
Enrica Tuveri Università Degli Studi Cagliari, Cittadella Universitaria di Monserrato Dipartimento di Scienze Chimiche 09042 Cagliari Italy

Search for other papers by Enrica Tuveri in
Current site
Google Scholar
PubMed Close
Pages:
909–922
Online Publication Date:
27 Sep 2007
Publication Date:
01 Dec 2007
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-007-7885-2
Keywords:
data; dimethylsulfoxide; DISQUAC model; excess enthalpy; group contribution
Restricted access

Abstract  

A flow microcalorimeter has been used to determine excess enthanlpies (HE) at 298.15 K for binary mixtures of dimethylsulfoxide (1)+alkylbenzenes (benzene, methylbenzene, ethylbenzene, n-propylbenzene and sec-propylbenzene, n-butylbenzene, sec-butylbenzene and tert-butylbenzene) or tetrachloromethane, trichloromethane, tetrachloroethane, dichloromethane and monochloroalkanes (1-chloropropane, 1-chlorobutane, 1-chloropentane, 1-chlorohexane) (2). These data with the data available in the literature on the molar excess enthalpies (HE), molar excess Gibbs energies (GE), activity coefficients at infinite dilution, γi∞, liquid-vapour equilibria (LVE) and liquid-liquid equilibria (LLE) for dimethylsulfoxide (DMSO)+n-alkanes, cyclohexane, benzene or alkylbenzenes (mono-, dialkyl-and trialkyl-) or tetrachloromethane, trichloromethane, dichloromethane and monochloroalkanes are treated in the framework of DISQUAC, an extended quasi-chemical group contribution theory. The systems are characterized by three types of contact surfaces: sulfoxide (S=O group), aliphatic (CH3, CH2, CH groups), cycloaliphatic (c-CH2 group), aromatic (C6H6, C6H5 groups) and chlorine (C1 group). Using a set of adjusted contact interchange energies parameters, structure dependent, the model provides a fairly consistent description of the thermodynamic properties as a function of concentration. The model may serve to predict missing data.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Apr 2024 8 0 0
May 2024 3 0 0
Jun 2024 18 0 0
Jul 2024 22 0 0
Aug 2024 13 0 0
Sep 2024 4 0 0
Oct 2024 0 0 0