Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 91: Issue 1
Thermal decomposition kinetics of the synthetic complex Pb(1,4-BDC)·(DMF)(H2O)
Authors:
J. Zhang

Search for other papers by J. Zhang in
Current site
Google Scholar
PubMed Close
,
J. Zeng

Search for other papers by J. Zeng in
Current site
Google Scholar
PubMed Close
,
Y. Liu

Search for other papers by Y. Liu in
Current site
Google Scholar
PubMed Close
,
L. Sun Chinese Academy of Sciences Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics Dalian 116023 P.R. China

Search for other papers by L. Sun in
Current site
Google Scholar
PubMed Close
,
F. Xu Chinese Academy of Sciences Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics Dalian 116023 P.R. China

Search for other papers by F. Xu in
Current site
Google Scholar
PubMed Close
,
W. You Liaoning Nomal Univ. Fac. Chem. and Chem. Engn. Dalian 116029 P.R. China

Search for other papers by W. You in
Current site
Google Scholar
PubMed Close
, and
Y. Sawada Tokyo Polytechnic University Department of Nanochemistry, Faculty of Engineering 1583 Iiyama, Atsugi Kanagawa 243-0297 Japan

Search for other papers by Y. Sawada in
Current site
Google Scholar
PubMed Close
Pages:
189–193
Online Publication Date:
12 Jul 2007
Publication Date:
01 Jan 2008
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-007-8494-9
Keywords:
apparent activation energy; kinetic model; TG-DTG; thermal decomposition
Restricted access

Abstract  

Pb(1,4-BDC)·(DMF)(H2O) (1,4-BDC=1,4-benzenedicarboxylate; DMF=dimethylformamide) has been synthesized and investigated by elemental analysis, FTIR spectroscopy, thermogravimetry (TG), derivative thermogravimetry (DTG). TG-DTG curves show that the thermal decomposition occurs in four stages and the corresponding apparent activation energies were calculated with the Ozawa-Flynn-Wall (OFW) and the Friedman methods. The most probable kinetic model function of the dehydration reaction of the compound has been estimated by the Coats-Redfern integral and the Achar-Bridly-Sharp differential methods in this study.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Dec 2024 12 1 1
Jan 2025 20 0 0
Feb 2025 32 0 0
Mar 2025 19 0 0
Apr 2025 14 0 0
May 2025 4 0 0
Jun 2025 0 0 0