Authors:
N. Nomura Sophia University Department of Chemistry 7-1 Kioicho, Chiyodaku Tokyo 102-8554 Japan

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Y. Zhang Sophia University Department of Chemistry 7-1 Kioicho, Chiyodaku Tokyo 102-8554 Japan

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T. Oi Sophia University Department of Chemistry 7-1 Kioicho, Chiyodaku Tokyo 102-8554 Japan

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Abstract  

The incorporation mechanism of Cs+ ions from CsNO3 into NH4Zr2(PO4)3 was studied on a mixture of CsNO3 and NH4Zr2(PO4)3 by powder X-ray diffraction analysis and by monitoring off-gases released from the mixture upon heating with a thermogravimetry analyzer connected to an infrared spectrometer. With increasing temperature, the decomposition of CsNO3 first started, followed by the conversion of NH4Zr2(PO4)3 to HZr2(PO4)3 with the release of NH3. At around 500°C, the Cs Zr2(PO4)3 phase started to appear as a result of the H+/Cs+ ion exchange. No Cs+ ion loss was observed at thermal treatment temperatures of 900°C and lower.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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