Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 91: Issue 3
Influence of carbon black on thermal properties and flammability of cross-linked elastomers
Authors:
Grażyna Janowska Technical University of Łódź Faculty of Chemistry, Institute of Polymer and Dye Technology Łódź Poland

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P. Rybiński Technical University of Łódź Faculty of Chemistry, Institute of Polymer and Dye Technology Łódź Poland

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Pages:
697–701
Online Publication Date:
16 Jun 2008
Publication Date:
01 Mar 2008
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-007-8621-7
Keywords:
carbon black; elastomers; fillers; flammability; nitrile rubbers; oxygen index; thermal analysis; thermal stability; thermal transitions
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Abstract  

The paper presents the results of testing thermal properties and combustibility of butadiene-acrylonitrile rubber vulcanizates with different contents of bounded acrylonitrile: Perbunan NT 1845 and Perbunan NT 3945 from Bayer. The rubbers were cross-linked by means of dicumyl peroxide. Four types of carbon black with different specific surfaces were used as fillers. The test results were obtained with the use the derivatograph, DSC-204 of Netzsch, measurements of flammability by the method of oxygen index and in air. The results of measurements have shown that the thermal stability and flammability of the vulcanizates under investigation are affected by the activity of solid phase and the degree of surface development as well as the flexibility of polymeric chain and the degree of its unsaturation. A clear relationship has been found between the thermal properties and flammability of the cross-linked butadiene-acrylonitrile rubbers.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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