Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 92: Issue 3
Fluorophenyl derivatives of elements II-VI groups
Phase transitions thermodynamics and growing films by CVD
Authors:
L. Zelenina

Search for other papers by L. Zelenina in
Current site
Google Scholar
PubMed Close
,
T. Chusova Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Prospect 3 630090 Novosibirsk Russia

Search for other papers by T. Chusova in
Current site
Google Scholar
PubMed Close
,
Yu. Stenin Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Prospect 3 630090 Novosibirsk Russia

Search for other papers by Yu. Stenin in
Current site
Google Scholar
PubMed Close
, and
V. Bakovets Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Prospect 3 630090 Novosibirsk Russia

Search for other papers by V. Bakovets in
Current site
Google Scholar
PubMed Close
Pages:
723–727
Online Publication Date:
02 Jul 2008
Publication Date:
01 Jun 2008
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-008-9026-y
Keywords:
CVD; enthalpy; entropy; fluorophenyl derivatives; scanning calorimetry; static method with a membrane-gauge manometer
Restricted access

Abstract  

The enthalpies and temperatures of melting of RSi(CH3)3, R4Si, R3P, R3As, R3Sb, R3Bi, R2Te and R2Hg (R=C6F5) were obtained by scanning calorimetry measurements. The pressure of the saturated and unsaturated vapors of RSi(CH3)3, R2Si(CH3)2, R4Si, R3Ga, R3P, R3As, R3Sb, R3Bi, R2Te and R2Hg has been measured by the static method with a membrane-gauge manometer. It was established that all investigated substances proceeded to vapor as monomers. Equations approximating the dependences of saturated vapor pressures on temperature and the enthalpies and entropies of vaporization were obtained. Grafite films with silicon intercalated up to 25 at.% were grown by CVD using R4Si as a precursor. These films showed semiconductor properties in the temperature interval 80–300 K.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Nov 2024 14 0 0
Dec 2024 7 0 0
Jan 2025 9 0 0
Feb 2025 18 0 0
Mar 2025 15 0 0
Apr 2025 9 0 0
May 2025 0 0 0