Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 92: Issue 3
Interactions of hexamethyltetrabutyl-substituted biladiene- a,c with cobalt(II) and zinc(II) acetates
Authors:
G. Guseva Russian Academy of Sciences Institute of Solution Chemistry 1 Akademicheskaya Street 153045 Ivanovo Russia

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E. Antina Russian Academy of Sciences Institute of Solution Chemistry 1 Akademicheskaya Street 153045 Ivanovo Russia

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A. Vyugin Russian Academy of Sciences Institute of Solution Chemistry 1 Akademicheskaya Street 153045 Ivanovo Russia

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Pages:
739–742
Online Publication Date:
02 Jul 2008
Publication Date:
01 Jun 2008
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-008-9016-0
Keywords:
biladiene-a,c; binuclear biligand complex; calorimetric titration; mononuclear complex; spectrophotometric titration
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Abstract  

The thermodynamics of the reaction of 1,3,7,13,17,19-hexamethyl-2,8,12,18-tetrabutylbiladiene-a,c (H2L) with cobalt(II) and zinc(II) acetates in dimethylformamide (298.15 K) was studied by spectrophotometric and calorimetric titration. It was found that H2L and Zn(II) form a mononuclear complex ZnL, and in the case of Co(II), a binuclear biligand complex Co2L2 is formed. Thermodynamic characteristics of the formation of Co(II) and Zn(II) complexes with biladiene-a,c in DMF at 298.15 K were determined.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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