Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 92: Issue 3
Thermochemistry of copper complex of 6-benzylaminopurine
Authors:
Y. Xu-Wu Northwest University, Xi’an Shaanxi Key Laboratory of Phsico-Inorganic Chemistry, Department of Chemistry 710069 Shaanxi China

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Z. Hang-Guo Northwest University, Xi’an Shaanxi Key Laboratory of Phsico-Inorganic Chemistry, Department of Chemistry 710069 Shaanxi China

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S. Wu-Juan Shaanxi University of Technology, Hanzhong College of Chemistry and Environment Science 723001 Shaanxi China

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W. Xiao-Yan Northwest University, Xi’an Shaanxi Key Laboratory of Phsico-Inorganic Chemistry, Department of Chemistry 710069 Shaanxi China

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G. Sheng-Li Northwest University, Xi’an Shaanxi Key Laboratory of Phsico-Inorganic Chemistry, Department of Chemistry 710069 Shaanxi China

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Pages:
961–965
Online Publication Date:
02 Jul 2008
Publication Date:
01 Jun 2008
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-006-7946-y
Keywords:
combustion energy; copper(II) complex of 6-benzylaminopurine; rotating-bomb calorimeter; standard enthalpy of formation
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Abstract  

The copper(II) complex of 6-benzylaminopurine (6-BAP) has been prepared with dihydrated cupric chloride and 6-benzylaminopurine. Infrared spectrum and thermal stabilities of the solid complex have been discussed. The constant-volume combustion energy, ΔcU, has been determined as −12566.92±6.44 kJ mol−1 by a precise rotating-bomb calorimeter at 298.15 K. From the results and other auxiliary quantities, the standard molar enthalpy of combustion, ΔcHmθ, and the standard molar of formation of the complex, ΔfHmθ, were calculated as −12558.24±6.44 and −842.50±6.47 kJ mol−1, respectively.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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