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  • 1 Nanjing University of Science and Technology School of Chemical Engineering Nanjing 210094 P.R. China
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Abstract  

The peak temperature (Tp) and different temperature (ΔT) are the basic information in the differential thermal analysis (DTA). Considering the kinetic relation and the heat equilibrium in DTA, a correctional differential kinetic equation (containing Tp and ΔT parameter) is proposed. In the dehydration reaction of CaC2O4·H2O, the activation energy calculated from the new equation showed some smaller than that from Kissinger equation, but some bigger than that from Piloyan equation.