Authors:
K. Rejitha Mahatma Gandhi University School of Chemical Sciences P.D. Hills Kottayam 686 560 Kerala India

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S. Mathew Mahatma Gandhi University School of Chemical Sciences P.D. Hills Kottayam 686 560 Kerala India

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Abstract  

Thermogravimetric techniques have been used to study the kinetics of thermal deamination of tris(ethylenediamine)nickel(II) sulphate. The complex was synthesized and characterized by various chemical and spectral techniques. Thermal decomposition studies were carried at different heating rates (5, 10, 15 and 20°C min−1) in dynamic air. The complex undergoes a four-stage decomposition pattern. The stages are not well resolved. Decomposition path can be interpreted as a two-stage deamination, and a two-stage decomposition. Reaction products at each stage were separated and identified by means of IR and XRD. The morphology of the complex and the residue were studied by means of SEM. Final residue of the decomposition was found to be crystalline NiO. The deamination kinetics was studied using model-free isoconversional methods viz., Friedman, Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS) methods. It is observed that the activation energy varies with the extent of conversion; indicating the complex nature of the deamination reaction.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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