Authors:
F. Käser

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B. Roduit AKTS AG TechnoArk 3 3960 Siders Switzerland

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Abstract  

A common scepticism towards the application of many product formulations results from the fact that their long-term stability is difficult to predict. In the present study we report on a new approach of kinetic analysis of the oxidation reactions of natural rubbers with and without stabiliser in an oxygen atmosphere at moderate temperatures using CL measurements carried out on a newly-developed instrumentation. The kinetic parameters of the oxidation process, calculated from the chemiluminescence’s signals by means of the differential isoconversional method of Friedman, were subsequently applied for the simulation of the rubber aging under different temperature profiles. The presented results are the first stage of research by using the chemiluminescence method to measure the oxidative aging of rubber and predicting the life time of rubber items.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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