Author:
V. Drebushchak
Restricted access

Abstract  

Conventional thermodynamic expression predicts that the isobaric heat capacity decreases with increasing pressure. In model calculations, heat capacity increases with pressure, decreases, or remains insensitive to pressure, depending on the model applied. The expression cannot be applied to the gases, but experimental data on gases show evidently that heat capacity increases with pressure. Considering the change in enthalpy along two different paths with identical starting and ending points, we derive new expression dCP/dPV, where α is the volume coefficient of thermal expansion and V is the molar volume. The expression predicts the increase in CP with pressure and can be applied to gases. The test of the new expression against accurate literature data on the heat capacity of air, gaseous and liquid, demonstrates its validity.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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Inorganic polymeric new materials

Author:
J. Davidovits