Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 95: Issue 2
Non-isothermal kinetics of free-radical polymerization of 2,2-dinitro-1-butyl acrylate
Authors:
S. Du Beijing Institute of Technology School of Chemical Engineering and the Environment Beijing 100081 China

Search for other papers by S. Du in
Current site
Google Scholar
PubMed Close
,
G. Zhang Beijing Institute of Technology School of Chemical Engineering and the Environment Beijing 100081 China

Search for other papers by G. Zhang in
Current site
Google Scholar
PubMed Close
,
H. Li Beijing Institute of Technology School of Chemical Engineering and the Environment Beijing 100081 China

Search for other papers by H. Li in
Current site
Google Scholar
PubMed Close
,
P. Wang Beijing Institute of Technology School of Chemical Engineering and the Environment Beijing 100081 China

Search for other papers by P. Wang in
Current site
Google Scholar
PubMed Close
, and
X. Wang China Academy of Engineering Physics Institute of Chemical Materials Mianyang 621900 China

Search for other papers by X. Wang in
Current site
Google Scholar
PubMed Close
Pages:
427–431
Online Publication Date:
12 Mar 2009
Publication Date:
01 Feb 2009
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-008-9253-2
Keywords:
2,2-dinitro-1-butyl acrylate; DSC; free-radical polymerization; kinetics
Restricted access

Abstract  

The free-radical bulk polymerization of 2,2-dinitro-1-butyl-acrylate (DNBA) in the presence of 2,2′-azobisisobutyronitrile (AIBN) as the initiator was investigated by DSC in the non-isothermal mode. Kissinger and Ozawa methods were applied to determine the activation energy (Ea) and the reaction order of free-radical polymerization. The results showed that the temperature of exothermic polymerization peaks increased with increasing the heating rate. The reaction order of non-isothermal polymerization of DNBA in the presence of AIBN is approximately 1. The average activation energy (92.91±1.88 kJ mol −1) obtained was smaller slightly than the value of Ea=96.82 kJ mol−1 found with the Barrett method.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Dec 2024 13 0 0
Jan 2025 66 0 0
Feb 2025 69 0 0
Mar 2025 48 0 0
Apr 2025 18 0 0
May 2025 3 0 0
Jun 2025 0 0 0