Authors:
V. Živanović Institute for the Technology of Nuclear and other Mineral Raw Materials 86 Franchet d’Esperey 11000 Belgrade Serbia

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S. Grujić Faculty of Technology and Metallurgy 4 Karnegijeva St. 11000 Belgrade Serbia

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M. Tošić Institute for the Technology of Nuclear and other Mineral Raw Materials 86 Franchet d’Esperey 11000 Belgrade Serbia

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N. Blagojević Faculty of Technology and Metallurgy 4 Karnegijeva St. 11000 Belgrade Serbia

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J. Nikolić Institute for the Technology of Nuclear and other Mineral Raw Materials 86 Franchet d’Esperey 11000 Belgrade Serbia

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Abstract  

The crystallization of K2O·TiO2·3GeO2 glass under non-isothermal condition was studied. In powdered glass with particle sizes less than 0.15 mm, surface crystallization was dominant and an activation energy of crystal growth of Ea,s=327±50 kJ mol−1 was calculated. In the size range 0.15 to 0.45 mm, both surface and volume crystallization occurred. For particle sizes >0.45 mm, volume crystallization dominated with spherulitic morphology of the crystals growth and Ea,v=359±64 kJ mol−1 was calculated.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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