Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 96: Issue 2
Relationship between properties of fluorinated graphite intercalates and matrix composition Part III. Intercalates with 1,2-dichloroethane
Authors:
D. Pinakov Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 Novosibirsk-90 630090 Russia

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V. Logvinenko Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 Novosibirsk-90 630090 Russia

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Yu. Shubin Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 Novosibirsk-90 630090 Russia

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G. Chekhova Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 Novosibirsk-90 630090 Russia

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Pages:
501–505
Online Publication Date:
05 Feb 2009
Publication Date:
01 May 2009
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-008-9534-9
Keywords:
fluorinated graphite; inclusion compounds; intercalates; isothermal kinetics; thermal stability
Restricted access

Abstract  

Inclusion compounds (intercalates) of fluorinated graphite matrix with 1,2-dichloroethane (C2FxBrz·yC2H4Cl2, x=0.49, 0.69, 0.87, 0.92, z≈0.01) were synthesized by guest substitution from acetonitrile to dichloroethane. The kinetics of the thermal decomposition (the 1st stage of filling→the 2nd stage of filling) was studied under isothermal conditions at 289–313 K. The relationship between the structure of host matrices with thermal properties and kinetic parameters of inclusion compounds is discussed.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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