Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 96: Issue 2
Thermal degradation of butyl acrylate-methyl acrylate-acrylic acid-copolymers
Authors:
Z. CzechSzczecin University of Technology Institute of Chemical Organic Technology Pulaskiego 10 70-322 Szczecin Poland

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R. PełechSzczecin University of Technology Institute of Chemical Organic Technology Pulaskiego 10 70-322 Szczecin Poland

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Pages:
583–586
Online Publication Date:
13 Nov 2008
Publication Date:
01 May 2009
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-008-9226-5
Keywords:
acrylic copolymer; pressure-sensitive adhesives; pyrolysis products; thermal degradation
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Abstract  

The thermal degradation of copolymers based on butyl acrylate-methyl acrylate-acrylic acid used as acrylic pressure-sensitive adhesives, especially for bonding of plasticizer containing materials, has been investigated using thermogravimetry and pyrolysis-gas chromatography at 250°C. It was observed that during the pyrolysis of butyl acrylate-methyl acrylate-acrylic acid copolymers unsaturated monomers as methyl acrylate, methyl methacrylate, butyl acrylate and butyl methacrylate were formed. During the side-chain butyl acrylate-methyl-acrylate-acrylic acid-copolymer degradation the presence of methyl alcohol and butyl alcohol was observed.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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