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  • 1 Laboratoire PBS, FRE 3101, LECAP, Institute for Materials Research, Université de Rouen, Faculté des Sciences, Avenue de l’Université BP 12, 76801 Saint Etienne du Rouvray, France
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Abstract  

Temperature modulated differential scanning calorimetry (TMDSC) and dynamic mechanical analysis (DMA) are used to calculate cooperative rearranging region (CRR) average sizes for drawn poly(ethylene terephthalate) (PET) with different draw ratios (λ) ranging from λ=1 to 4, according to Donth’s approach. It is shown for both studies that the CRR size decreases when increases, due to the amorphous phase confinement by the crystals generated during the drawing. However, differences observed between the values calculated from TMDSC and DMA investigations are explained by the differences between a mechanical uniaxial dynamic solicitation (DMA) or a thermal solicitation (TMDSC) in terms of cooperative rearrangements at the glass transition.

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)