Geopolymers
Inorganic polymeric new materials
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Mauro da Silva
Mauro da Silva
Universidade de São Paulo Instituto de Química CP 26077 Sao Paulo SP 05513-970 Brazil
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Flávio de Souza Carvalho
Flávio de Souza Carvalho
Universidade de São Paulo Instituto de Geociências Sao Paulo SP Brazil
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Tereza da Silva Martins
Tereza da Silva Martins
Universidade Federal de São Paulo Departamento de Ciências Exatas e da Terra Sao Paulo SP Brazil
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Márcia de Abreu Fantini
Márcia de Abreu Fantini
Universidade de São Paulo Departamento de Física Aplicada, Instituto de Física Sao Paulo SP Brazil
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Paulo Isolani
Paulo Isolani
Universidade de São Paulo Instituto de Química CP 26077 Sao Paulo SP 05513-970 Brazil
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Abstract
Two series of lanthanide oxides with different morphologies were synthesized through calcinations of two types of citrate polymeric precursors. These oxides were characterized by XRD patterns, SEM electronic microscopy, and N2 adsorption isotherms. SEM microscopy analysis showed that the calcination of crystalline fibrous precursors [Ln2(LH)3·2H2O] (L = citrate) originated fibrous shaped particles. On the other hand, the calcination of irregular shaped particles of precursors [LnL·xH2O] originated irregular shaped particles of oxide, pointing out a morphological template effect of precursors on the formation of the respective oxides.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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