Authors:
Agnieszka W&grzyn Jagiellonian University Faculty of Chemistry Ingardena 3 30 060 Krakow Poland

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Alicja Rafalska-&asocha Jagiellonian University Faculty of Chemistry Ingardena 3 30 060 Krakow Poland

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Dorota Majda Jagiellonian University Regional Laboratory for Physicochemical Analyses and Structural Research Ingardena 3 30 060 Krakow Poland

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Roman Dziembaj Jagiellonian University Faculty of Chemistry Ingardena 3 30 060 Krakow Poland
Jagiellonian University Regional Laboratory for Physicochemical Analyses and Structural Research Ingardena 3 30 060 Krakow Poland

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Helmut Papp University of Leipzig Institute of Technical Chemistry Linnéstraße 3 04103 Leipzig Germany

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Abstract

A series of Mg/Al hydrotalcites with tailored content of carbonate and nitrate anions was prepared using precipitation method. A part of the obtained materials was additionally crystallized in hydrothermal conditions. Different hydrotalcite phases or domains may co-exist within one sample obtained at controlled conditions. Decomposition mechanism studied in situ (DRIFT, XRD) was different for the samples with high concentration of interlayer nitrate anions than for carbonate-containing sample. TG-QMS study of hydrothermally treated samples provided more precise data for quantitative description of decomposition steps of Mg/Al hydrotalcites containing different mixtures of nitrate and carbonate anions.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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