Authors:
K. Jisha S.N. College Department of Chemistry Kollam Kerala India

Search for other papers by K. Jisha in
Current site
Google Scholar
PubMed
Close
,
S. Suma S.N. College Department of Chemistry Kollam Kerala India

Search for other papers by S. Suma in
Current site
Google Scholar
PubMed
Close
, and
M. Sudarsanakumar M.G College Department of Chemistry Thiruvananthapuram Kerala India

Search for other papers by M. Sudarsanakumar in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract

Zirconyl complexes of hippuric acid (C9H9NO3, hipH) and monophenylbutazone (4-butyl-1-phenyl-3,5-pyrazolidinedione, MPB) were prepared using ZrOCl2 · 8H2O and ZrO(NO3)3 · xH2O and characterized by elemental analysis, molar conductance measurement and IR, UV–Vis and NMR spectral methods. Thermal decomposition behaviour was studied by thermogravimetry. The second harmonic generation (SHG) conversion efficiency of hippuric acid complexes was also studied.

  • 1.

    Capllonch MC Garcia-Raso A Terron A Apella MC Espinosa E Molins E . Interactions of d10 metal ions with hippuric acid and cytosine X-ray structure of the first cadmium (II)-amino acid derivative-nucleobase ternary compound. J Inorg Biochem. 2001; 85: 1738 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 2.

    Sgarabotto P Bisceglie F Pelosi G Abdel-Rahman L . Synthesis, x-ray crystal structures and characterization of copper(II)-2,2’-bipyridyl derivatives of (4-amino)-hippuric acid and of L-proline. Polyhedron. 1999; 8: 250510 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3.

    Terron A Fiol JJ Herrero LA Garcia-Rasso A Apella MC Caubet A , et al. Metal-amino acid (or peptide)-nuclesoide (or related bases) ternary complexes. An Quim Int Ed. 1997; 93: 607.

    • Search Google Scholar
    • Export Citation
  • 4.

    Garcia-Raso A Fiol JJ Adrover B Moreno V Molins E Mata L . Synthesis and structure of isocytosine ternary copper(II) complexes. Dalton Trans J Chem Soc. 1998; 10316.

    • Search Google Scholar
    • Export Citation
  • 5.

    Ashby CIH Paton WF Brown TL . Nitrogen-14 nuclear quadrupole resonance spectra of the coordinated amino group and of coordinated imidazole. Crystal and molecular structures of chloroglycylglycinato(imidazole)cadmium. J Am Chem Soc. 1980; 102: 29908 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6.

    Morelock MM Good ML Trefonas LM Karraker DG Maleki L Eichelberger HR , et al. Metal ion complexes of alpha amino acids. Structure and magnetic properties of the nickel and cobalt hippurates. Pseudo-one-dimensional magnetic systems. J Am Chem Soc. 1979; 101: 485866 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7.

    Grewe H Udupa MR Kerbs B . Crystal and molecular structure of bis(N-benzoylglycinato)triaquozinc(II) dihydrate. Inorg Chim Acta. 1982; 63: 11924 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8.

    Brzyska W Hakim M . Thermal decomposition of Co(II), Ni(II), Cu(II) and Zn(II) hippurates. J Therm Anal Calorim. 1990; 36: 84753.

  • 9.

    Brzyska W Hakim M . Thermal decomposition of Y, La and light lanthanide complexes of hippuric acid. J Therm Anal. 1988; 34: 4753 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10.

    Refat MS Teleb SM Sadeek SA Khater HM El-Megharbel SM . Synthesis and characterization of some hippurato rare earth metal complexes. J Kor Chem Soc. 2005; 49: 326168.

    • Search Google Scholar
    • Export Citation
  • 11.

    Sadeek SA Refat MS Teleb SM Megharbel EI . Synthesis and characterization of V(III), Cr(III) and Fe(III) hippurates. J Mol Struct. 2005; 737: 13945 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12.

    Allan JR Dalrymple J . The thermal, spectral and magnetic studies of hippuric acid compounds of cobalt (II), nickel (II), copper (II) and zinc (II) ions. Thermochim Acta. 1991; 185: 839 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13.

    Khayyal MT El-Ghazaly M El-Khatib AS Hatem A . Tolerability of mofebutazone in asthmatic patients. Int J Clin Pharmacol Res. 1995; 15: 14551.

    • Search Google Scholar
    • Export Citation
  • 14.

    Paradies HH Ziedrich KH Hans H , Flaeming. Zur-keto-enol-tomtomerie von 1-phenyl 4n-butyl-pyrazolidin-(3,5)dion. Acta Pharm Technol. 1987; 33: 1808.

    • Search Google Scholar
    • Export Citation
  • 15.

    Suma S Sudarsanakumar MR Nair CGR Prabhakaran CP . Synthesis and characterization of chromium(III), manganese(III), iron(III), cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II) and mercury(II) complexes of monophenylbutazone. Indian J Chem. 1994; 33A:11079.

    • Search Google Scholar
    • Export Citation
  • 16.

    Kurtz SK Perry TT . A powder technique for the evaluation of nonlinear optical materials. J Appl Phys. 1968; 39: 3798813 .

  • 17.

    Kumar G Srivastava M . Spectral and magnetochemical studies of nickel(II) and cobalt(II) complexes of hippuric acid. Rev Chim Miner. 1979; 16: 148.

    • Search Google Scholar
    • Export Citation
  • 18.

    Nakamoto K . Infrared and Raman spectra of inorganic and coordination compounds. 4th ed. New York: Wiley; 1986.

  • 19.

    Refat MS EI Korashy SA Ahmed S . Synthesis and characterization of Mn(II), Au(III) and Zr(IV) hippurates complexes. Spectrochim Acta Part A Biomol Spectrosc. 2008; 70: 8409 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20.

    Dro&d&-Cie&la E Ma&ecki A . Mechanism of thermal decomposition of zirconyl oxalate ZrOC2O4. J Therm Anal Calorim. 2008;92: 93944 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 21.

    Coats AW Redfern JP . Kinetic parameters from thermogravimetric data. Nature. 1964; 201: 689 .

  • 22.

    MacCallum JR Tanner . The kinetics of thermogravimetry. J Eur Polym. 1970; 6: 10337 .

  • 23.

    Muraleedharan Nair MK Radhakrishnan PK . Thermal decomposition kinetics of lanthanum complexes of 1,2-(Diimino-4’-Antipyrinyl)ethane. Thermochim Acta. 1997; 292: 11522 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 24.

    Thankamony M Sindhu Kumari B Rijulal G Mohanan K . Lanthanum(III) chloride complexes with heterocyclic Schiff bases. J Therm Anal Calorim. 2009; 95: 25966 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jul 2024 42 0 0
Aug 2024 28 0 0
Sep 2024 24 0 0
Oct 2024 64 0 0
Nov 2024 46 0 0
Dec 2024 36 0 0
Jan 2025 9 0 0