Geopolymers
Inorganic polymeric new materials
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Shao Luan
Shao Luan
East China University of Science and Technology Research Center of Analysis and Test, School of Chemistry and Molecular Engineering Shanghai 200237 People's Republic of China
East China University of Science and Technology Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering Shanghai 200237 People's Republic of China
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East China University of Science and Technology Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering Shanghai 200237 People's Republic of China
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Yi Zhu
Yi Zhu
East China University of Science and Technology Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering Shanghai 200237 People's Republic of China
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Yu Jia
Yu Jia
East China University of Science and Technology Department of Chemistry, School of Chemistry and Molecular Engineering Shanghai 200237 People's Republic of China
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Qing Cao
Qing Cao
East China University of Science and Technology Research Center of Analysis and Test, School of Chemistry and Molecular Engineering Shanghai 200237 People's Republic of China
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Abstract
A complex of thiourea and bismuth trichloride has been synthesized. Its composition is Bi3Cl9[SC(NH2)2]7. Crystallographic data are a = 7.141(2) Å, b = 8.820(3) Å, c = 16.365(5) Å, & = 99.389(4)°, β = 95.422(4)°, γ = 106.177(4)°, triclinic system. There are the mononuclear anion [BiCl5SC(NH2)2]2− and the dinuclear cation {Bi2Cl4[SC(NH2)2]6}2& with the Bi–Cl–Bi bridge bonds in the complex. The electric conductance of the absolute methanol solution contained the complex indicates that the complex is an ionic compound. Raman spectra indicate that the bismuth ion is coordinated by the sulfur atoms of the thiourea. The thermal analysis verifies the structure of complex. The TG–MASS curves show the structure rearrangement in the complex at about 118 °C. The DSC curves and calculation means that the structure rearrangement is irreversible.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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