Geopolymers
Inorganic polymeric new materials
Author:
Authors:
and
M. Sovizi
M. Sovizi
Malek Ashtar University of Technology Faculty of Material and Manufacturing Technologies P.O. Box 16765-3345 Tehran Iran
Search for other papers by M. Sovizi in
Current site
Google Scholar
PubMed
Search for other papers by M. Sovizi in
Current site
Google Scholar
PubMed
K. Anbaz
K. Anbaz
Imam Hossein University Department of Chemistry Tehran Iran
Search for other papers by K. Anbaz in
Current site
Google Scholar
PubMed
Search for other papers by K. Anbaz in
Current site
Google Scholar
PubMed
Abstract
In this paper, the thermal behaviours of two organophosphorous compounds, N,N-dimethyl-N′,N′-diphenylphosphorodihydrazidic (NDD) and diphenyl amidophosphate (DPA), were studied by thermogravimetery (TG), differential thermal analysis (DTA) and differential scanning calorimetery (DSC) techniques under non-isothermal conditions. The results showed that NDD melts about 185 °C before it decomposes. NDD decomposition occurs in two continuous steps, in the 190–410 °C temperature range. First thermal degradation stage for NDD results a broad exothermic peak in the DTA curve that is continued with a small exothermic peak at the end of decomposition process. On the other hand, applying TG-DTA techniques indicates that DPA melts about 150 °C before it decomposes. This compound decomposes in the temperature range of 230 to 330 °C in two steps. These steps are endothermic and exothermic, respectively. Activation energy and pre-exponential factor for the first step of decomposition of each compound were found by means of Kissinger method and were verified by Ozawa–Flynn–Wall method. Activation energy obtained by Kissinger method for the first stage of NDD and DPA decompositions are 138 and 170 KJ mol−1, respectively. Finally, the thermodynamic parameters (ΔG&, ΔH& and ΔS&) for first step decomposition of investigated organophosphorous were determined.
ProCite
RefWorks
Reference Manager
BibTeX
Zotero
EndNote
-
1.
Jamal E Shashidhar N Adrea M William S . Prediction of organophosphorus acetylcholinesterase inhibition using three-dimensional quantitative structure-activity relationship (3D-QSAR) methods. Toxicol Sci. 2001; 63: 223 .
-
2.
Kamil K Jirl B Jirl C Jirl K . Synthesis of a new reactivator of tabun-inhibited etylcholinesterase. Bioorg Med Chem Lett. 2003; 13: 3545 .
-
3.
Ghadimi S Mousavi S Javani Z . Structure-activity study of phosphoramido acid esters as acetylcholinesterasf inhibitors. J Enzym Inhib Med Chem. 2008; 23: 213 .
-
4.
Hansch C Deutsch E . The use of substitution constants in the study of structure-activity relationships in cholinesterase inhibitors. Biochim Biophys Acta. 1966; 126: 117 .
-
5.
Hosa N Radic Z Tsigeling I Berman H Quinn D Taylor P . Aspartate74 as a primary determinant in acetylcholinesterase governing specificity to cationic organophosphates. Biochem J. 1996; 35: 995.
-
6.
Singh AK . Quantitative structure-activity relationships for phosphoramidothioate toxicity in housefly. Comp Biochem Phys A. 1999; 123: 241–55.
-
7.
Basak S Magnuson V Niemi G Regal R Veith G . Topological indices: their nature, mutual relatedness, and applications. Math Model. 1986; 8: 300 .
-
8.
Hosseini SG Pourmortazavi SM Hajimirsadeghi SS . Thermal decomposition of pyrotechnic mixtures containing sucrose with either potassium chlorate or potassium perchlorate. Combust Flame. 2005; 141: 322 .
-
9.
Pourmortazavi SM Hajimirsadeghi SS Kohsari I Fathollahi M Hosseini SG . Thermal decomposition of pyrotechnic mixtures containing either aluminum or magnesium powder as fuel. Fuel. 2008; 87: 244 .
-
10.
Pourmortazavi SM Hosseini SG Hajimirsadeghi SS Fareghi Alamdari R . Investigation on thermal analysis of binary zirconium/oxidant pyrotechnic systems. Combust Sci Tech. 2008; 180: 2093 .
-
11.
Pourmortazavi SM Hajimirsadeghi SS Hosseini SG . Characterization of the aluminum/potassium chlorate mixtures by simultaneous thermogravimetry—differential thermal analysis. J Therm Anal Calorim. 2006; 84: 557 .
-
12.
Hajimirsadeghi SS Teimouri MB Rahimi-Nasrabadi M Dehghanpour S . Non-isothermal kinetic study of the thermal decomposition of N-&bis&benzyl(methyl)amino&phosphoryl&-2,2-dichloroacetamide and N-&bis&dibenzylamino&phosphoryl&-2,2-dichloroacetamide. J Therm Anal Cal. 2009. .
-
13.
Senneca O Scherillo F Nunziata A . Thermal degradation of pesticides under oxidative conditions. J Anal Appl Pyrolysis. 2007; 80: 61 .
-
14.
Andreozzi R Ialongo G Marotta R Sanchirico R . Thermal decomposition of ethyl parathion. J Loss Prevent Proc. 1999; 12: 315 .
-
15.
Fathollahi M Pourmortazavi SM Hosseini SG . Particle size effects on thermal decomposition of energetic material. J Energ Mater. 2008; 26: 52 .
-
16.
Bohn MA . Kinetic modeling of the concentrations of the stabilizer DPA and some of its consecutive products as function of time and temperature. J Therm Anal Calorim. 2001; 65: 103 .
-
17.
Kohsari I Pourmortazavi SM Hajimirsadeghi SS . Non-isothermal kinetic study of the thermal decomposition of diaminoglyoxime and diaminofurazan. J Therm Anal Calorim. 2007; 89: 543 .
-
18.
Eslami A Hosseini SG Pourmortazavi SM . Thermoanalytical investigation on some boron-fuelled binary pyrotechnic systems. Fuel. 2008; 87: 3339 .
-
19.
Edmundson RS . Dictionary of organophosphorus compounds, Published by CRC Press, 1988, ISBN 0412257904, 9780412257902.
-
20.
Kissinger HE . Reaction kinetics in differential thermal analysis. Anal Chem. 1957; 29: 1702 .
-
21.
Ozawa T . A new method of analyzing thermogravimetric data. Bull Chem Soc Jpn. 1965; 38: 1881 .
-
22.
Hatakeyama T Quinn FX . Thermal analysis: fundamentals and applications to polymer science. New York: Wiley; 1994.
-
23.
Rong L Binke N Yuan W Zhengquan Y Rongzu H . Estimation of the critical temprature of thermal explosion for the highly nitrated nitrocellulose using non-isothermal DSC. J Therm Anal Calorim. 1999; 58: 369 .
-
24.
Pineda EAG Ferrarezi ADM Ferrarezi JG Hechenleitner AAW . Thermal decomposition of enalapril maleate studied by dynamic isoconversional method. J Therm Anal Calorim. 2005; 79: 259 .
-
25.
ASTM E 698, Test methods for Arrhenius kinetic constants for thermally unstable materials.
-
26.
Pourmortazavi SM Kohsari I Teimouri MB Hajimirsadeghi SS . Thermal behaviour kinetic study of the dihydroglyoxime and dichloroglyoxime. Mater Lett. 2007; 61: 4670 .
-
27.
Criado JM Perez-Maqueda LA Sanchez-Jimenez PE . Dependence of the preexponential factor on temperature. J Therm Anal Calorim. 2005; 82: 671 .
-
28.
Pourmortazavi SM Hosseini SG Rahimi-Nasrabadi M Hajimirsadeghi SS Momenian H . Effect of nitrate content on thermal decomposition of nitrocellulose. J Hazard Mater. 2009; 162: 1141 .
-
29.
Krabbendam-LaHaye ELM de Klerk WPC Krämer RE . The kinetic behaviour and thermal stability of commercially available explosives. J Therm Anal Calorim. 2005; 80: 495 .
To see the editorial board, please visit the website of Springer Nature.
Manuscript Submission: HERE
For subscription options, please visit the website of Springer Nature.
| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
Monthly Content Usage
| Abstract Views | Full Text Views | PDF Downloads | |
|---|---|---|---|
| Jul 2024 | 22 | 0 | 0 |
| Aug 2024 | 33 | 0 | 0 |
| Sep 2024 | 54 | 1 | 0 |
| Oct 2024 | 161 | 0 | 0 |
| Nov 2024 | 33 | 0 | 0 |
| Dec 2024 | 33 | 0 | 0 |
| Jan 2025 | 7 | 0 | 0 |
Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
Author:
Copyright Akadémiai Kiadó AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
Powered by PubFactory