Geopolymers
Inorganic polymeric new materials
Author:
Authors:
,
, and
Mohd Abu Bakar
Mohd Abu Bakar
Loughborough University Department of Chemical Engineering Loughborough Leicestershire LE11 3TU UK
Search for other papers by Mohd Abu Bakar in
Current site
Google Scholar
PubMed
Search for other papers by Mohd Abu Bakar in
Current site
Google Scholar
PubMed
Zoltan Nagy
Zoltan Nagy
Loughborough University Department of Chemical Engineering Loughborough Leicestershire LE11 3TU UK
Search for other papers by Zoltan Nagy in
Current site
Google Scholar
PubMed
Search for other papers by Zoltan Nagy in
Current site
Google Scholar
PubMed
Christopher Rielly
Christopher Rielly
Loughborough University Department of Chemical Engineering Loughborough Leicestershire LE11 3TU UK
Search for other papers by Christopher Rielly in
Current site
Google Scholar
PubMed
Search for other papers by Christopher Rielly in
Current site
Google Scholar
PubMed
Abstract
A combination of differential scanning calorimetry and hot-stage microscopy with image analysis has been used to investigate the polymorphism of sulfathiazole. The use of light intensity profiles obtained from the HSM images, as an alternative way to present results of the HSM analysis, was found to be useful in describing and verifying thermal events. The approach provides a unique insight into the polymorphic transformations and thermal behaviour exhibited by this compound. The results of the experiments show that sulfathiazole tends to crystallise as mixtures of polymorphs, even though the literature methods for producing pure polymorph were followed.
ProCite
RefWorks
Reference Manager
BibTeX
Zotero
EndNote
-
1.
Karpinski PH . Polymorphism of active pharmaceutical ingredients. Chem Eng Technol. 2006; 29: 233–7 .
-
2.
Hilfiker R Blatter F von Raumer M . Relevance of solid-state properties for pharmaceutical products. In: Hilfiker R, editor. Polymorphism in the pharmaceutical industry. Weinheim: Wiley-VCH Verlag GmbH & Co; 2006. p. 1–18.
-
3.
Kordikowski A Shekunov T York P . Polymorph control of sulfathiazole in supercritical CO2. Pharm Res. 2001;18: 682–8 .
-
4.
Pollanen K Hakkinen AW Reinikainen SP Louhi-Kultanen A Nystrom L . A study on batch cooling crystallization of sulphathiazole - process monitoring using ATR-FTIR and product characterization by automated image analysis. Chem Eng Res Des. 2006; 84: 47–59 .
-
5.
Abu Bakar MR Nagy ZK Saleemi AN Rielly CD . The impact of direct nucleation control on crystal size distribution in pharmaceutical crystallization processes. Cryst Growth Des. 2009; 9: 1378–84 .
-
6.
Woo XY Nagy ZK Tan RBH Braatz RD . Adaptive concentration control of cooling and antisolvent crystallization with laser backscattering measurement. Cryst Growth Des. 2009; 9: 182–91 .
-
7.
Nagy ZK Chew JW Fujiwara M Braatz RD . Comparative performance of concentration and temperature controlled batch crystallizations. J Process Control. 2008; 18: 399–407 .
-
8.
Craig DQM Reading M . Thermal analysis of pharmaceuticals. Boca Raton, FL: CRC Press; 2007.
-
9.
Barnes AF Hardy MJ Lever TJ . A review of the applications of thermal methods within the pharmaceutical industry. J Therm Anal. 1993; 40: 499–509 .
-
10.
Giron D . Applications of thermal analysis in the pharmaceutical industry. J Pharm Biomed Anal. 1986; 4: 755–70 .
-
11.
Giron D . Thermal analysis and calorimetric methods in the characterization of polymorphs and solvates. Thermochim Acta. 1995; 248: 1–59 .
-
12.
Giron D . Contribution of thermal methods and related techniques to the rational development of pharmaceuticals - part 1. PSTT. 1998; 1: 191–9.
-
13.
Reading M Craig DQM . Principles of differential scanning calorimetry. In: Craig DQM, Reading M, editors. Thermal analysis of pharmaceuticals. Boca Raton, FL: CRC Press; 2007. p. 1–20.
-
14.
Clas S-D Dalton CR Hancock BC . Differential scanning calorimetry: applications in drug development. PSTT. 1999; 2: 311–20.
-
15.
Vitez IM Newman AW Davidovich M Kiesnowski C . The evolution of hot-stage microscopy to aid solid-state characterizations of pharmaceutical solids. Thermochim Acta. 1998; 324: 187–96 .
-
16.
Marthi K Ács M Pokol G Tomor K Eröss-Kiss KJ . DSC studies on the polymorphism and pseudopolymorphism of pharmaceutical substances: a complex system for studying physico-chemical behaviour of binary mixtures. J Therm Anal. 1992; 38: 1017–25 .
-
17.
Vitez IM Newman AW . Thermal microscopy. In: Craig DQM, Reading M, editors. Thermal analysis of pharmaceuticals. Boca Raton, FL: CRC Press; 2007. p. 221–64.
-
18.
Patience DB Dell’Orco PC Rawlings JB . Optimal operation of a seeded pharmaceutical crystallization with growth-dependent dispersion. Org Proc Res Dev. 2004; 8: 609–15 .
-
19.
Calderon De Anda J Wang XZ Roberts KJ . Multi-scale segmentation image analysis for the in-process monitoring of particle shape with batch crystallisers. Chem Eng Sci. 2005; 60: 1053–65 .
-
20.
Wang XZ Roberts KJ Ma C . Crystal growth measurement using 2D and 3D imaging and the perspectives for shape control. Chem Eng Sci. 2008; 63: 1173–84 .
-
21.
Simon LL Nagy ZK Hungerbuehler K . Comparison of external bulk video imaging with focused beam reflectance measurement and ultra-violet visible spectroscopy for metastable zone identification in food and pharmaceutical crystallization processes. Chem Eng Sci. 2009; 64: 3344–51 .
-
22.
Simon LL Nagy ZK Hungerbuehler K . Endoscopy-based in situ bulk video imaging of batch crystallization processes. Org Proc Res Dev. 2009. .
-
23.
Giron D . Investigations of polymorphism and pseudo-polymorphism in pharmaceuticals by combined thermoanalytical techniques. J Therm Anal Calorim. 2001; 64: 37–60 .
-
24.
Giron D . Applications of thermal analysis and coupled techniques in pharmaceutical industry. J Therm Anal Calorim. 2002; 68: 335–57 .
-
25.
Pommerenke K . DSC and thermomicroscopy combined. Am Lab. 2000; 32: 30–2.
-
26.
Richardson MF Yang Q-C Novotny-Bregger E Dunitz JD . Conformational polymorphism of dimethyl 3,6-dichloro-2,5-dihydroxyterephthalate. II. Structural, thermodynamic, kinetic and mechanistic aspects of phase transformations among the three crystal forms. Acta Crystallogr. 1990; B46: 653–60.
-
27.
Wiedemann HG Bayer G . Application of simultaneous thermomicroscopy/DSC to the study of phase diagrams. J Therm Anal. 1985; 30: 1273–81 .
-
28.
Wiedemann HG Felder-Casagrande S . Thermomicroscopy. In: Brown ME, editor. Handbook of thermal analysis and calorimetry, vol. 1: Principles and practice. Amsterdam: Elsevier Science B.V.; 1998. p. 473–96.
-
29.
da Silva RMF De Medeiros FPM Nascimento TG Macedo RO Neto PJR . Thermal characterization of indinavir sulfate using TG, DSC and DSC-photovisual. J Therm Anal Calorim. 2009; 95: 965–8 .
-
30.
Apperley DC Fletton RA Harris RK Lancaster RW Tavener S Threlfall TL . Sulfathiazole polymorphism studied by magic-angle spinning NMR. J Pharm Sci. 1999; 88: 1275–80 .
-
31.
Chan FC Anwar J Cernik R Barnes P Wilson RM . Ab initio structure determination of sulfathiazole polymorph V from synchrotron X-ray powder diffraction data. J Appl Crystallogr. 1999; 32: 436–41 .
-
32.
Hughes DS Hursthouse MB Threlfall T Tavener S . A new polymorph of sulfathiazole. Acta Crystallogr C. 1999; 55: 1831–3 .
-
33.
Blagden N Davey RJ Lieberman HF Williams L Payne R Roberts R , et al. Crystal chemistry and solvent effects in polymorphic systems: sulfathiazole. J Chem Soc, Faraday Trans. 1998; 94: 1035–44 .
-
34.
Anwar J Tarling SE Barnes P . Polymorphism of sulphathiazole. J Pharm Sci. 1989; 78: 337–42 .
-
35.
Lagas M Lerk CF . The polymorphism of sulphathiazole. Int J Pharm. 1981; 8: 25–33 .
-
36.
Mesley RJ . The polymorphism of sulfathiazole. J Pharm Pharm. 1971; 23: 687–94.
-
37.
Hughes DS Hursthouse MB Lancaster RW Tavener S Threlfall T Turner P . How many polymorphs has sulfathiazole? Proposals for reporting crystallographic data of polymorphs. J Pharm Pharm. 1997; 49: 20.
-
38.
Anderson JE Moore S Tarczynski F Walker D . Determination of the onset of crystallization of N1-2-(thiazolyl)sulfanilamide (sulfathiazole) by UV-Vis and calorimetry using an automated reaction platform; subsequent characterization of polymorphic forms using dispersive Raman spectroscopy. Spectrochim Acta A. 2001; 57: 1793–808 .
-
39.
Aaltonen J Rantanen J Siiria S Karjalainen M Jorgensen A Laitinen N , et al. Polymorph screening using near-infrared spectroscopy. Anal Chem. 2003; 75: 5267–73 .
-
40.
Hakkinen A Pollanen K Karjalainen M Rantanen J Louhi-Kultanen M Nystrom L . Batch cooling crystallization and pressure filtration of sulphathiazole: the influence of solvent composition. Biotechnol Appl Biochem. 2005; 41: 17–28 .
-
41.
Khoshkhoo S Anwar J . Crystallization of polymorphs: the effect of solvent. J Phys D. 1993; 26: B90–3 .
-
42.
Gelbrich T Hughes DS Hursthouse MB Threlfall TL . Packing similarity in polymorphs of sulfathiazole. Cryst Eng Comm. 2008; 10: 1328–34.
-
43.
Lever T . Optimizing DSC experiments. In: Craig DQM, Reading M, editors. Thermal analysis of pharmaceuticals. Boca Raton, FL: CRC Press; 2007. p. 24–51.
-
44.
Urakami K Shono Y Higashi A Umemoto K Godo M . Estimation of transition temperature of pharmaceutical polymorphs by measuring heat of solution and solubility. Bull Chem Soc Jpn. 2002; 75: 1241–5 .
-
45.
Miller RP Sommer G . A hot stage microscope incorporating a differential thermal analysis unit. J Sci Instrum. 1966; 43: 293–7 .
-
46.
Howard KS Nagy ZK Saha B Robertson AL Steele G . Combined PAT-solid state analytical approach for the detection and study of sodium benzoate hydrate. Org Proc Res Dev. 2009; 13: 590–7 .
-
47.
Warrington SB . Simultaneous thermal analysis techniques. In: Haines PJ, editor. Principles of thermal analysis and calorimetry. Cambridge: The Royal Society of Chemistry; 2002. p. 166–89 .
To see the editorial board, please visit the website of Springer Nature.
Manuscript Submission: HERE
For subscription options, please visit the website of Springer Nature.
| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
Monthly Content Usage
| Abstract Views | Full Text Views | PDF Downloads | |
|---|---|---|---|
| Jul 2024 | 8 | 0 | 0 |
| Aug 2024 | 24 | 0 | 0 |
| Sep 2024 | 33 | 0 | 0 |
| Oct 2024 | 145 | 0 | 0 |
| Nov 2024 | 57 | 0 | 0 |
| Dec 2024 | 34 | 0 | 0 |
| Jan 2025 | 13 | 0 | 0 |
Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
Author:
Copyright Akadémiai Kiadó AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
Powered by PubFactory