View More View Less
  • 1 Universidade de Brasília QuiCSI Team, Instituto de Química Caixa Postal 4478 70904-970 Brasília DF Brazil
  • | 2 Laboratório de Produtos Florestais SCEN trecho 02 70818-900 Brasília DF Brazil
  • | 3 Universidade de Brasília Faculdade Unidade de Planaltina 73300-000 Planaltina DF Brazil
Restricted access

Abstract

Brazilian sawdust samples (Caryocar spp.; Manilkara spp.; and Tabebuia spp.) have been used for Cr(VI) adsorption from water. The series of adsorption isotherms were adjusted to modified Langmuir equation. Thermodynamic data of interactions were studied by the calorimetric titration of Cr(VI) in aqueous solution. All liquid/solid interface adsorptions were entalpically and entropically driven. These sawdust samples were also used to remove chromium from tannery wastewater. The application of Caryocar spp.; Manilkara spp.; and Tabebuia spp. reduced the amount of chromium from 2.11 ± 0.18 mg L−1 to 1.15 ± 0.10; 0.29 ± 0.02 and 0.26 ± 0.02 mg L−1, respectively.

  • 1.

    Prado AGS . Green chemistry, the chemical challenges of the new millenium. Quim Nova. 2003; 26: 73844.

  • 2.

    Evangelista SM Deoliveira E Castro GR Zara LF Prado AGS . Hexagonal mesoporous silica modified with 2-mercaptothiazoline for removing mercury from water solution. Surf Sci. 2007; 601: 2194202 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3.

    Prado AGS Miranda BS Jacintho GVM . Interaction of indigo carmine dye with silica modified with humic acids at solid/liquid interface. Surf Sci. 2003; 542: 27682 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4.

    Prado AGS Faria EA Souzade JR Torres JD . Ammonium complex of niobium as a precursor for the hydrothermal preparation of cellulose acetate/Nb2O5 photocatalyst. J Mol Catal A. 2005;237: 1159 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5.

    Prado AGS Miranda BS Zara LE . Adsorption and thermochemical data of divalent cations onto silica gel surface modified with humic acid at solid/liquid interface. J Hazard Mater. 2005; 120: 2437 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6.

    Roldan PS Alcantara IL Castro GR Rocha JC Padilha CCF Padilha PM . Determination of Cu, Ni, and Zn in fuel ethanol by FAAS after enrichment in column packed with 2-aminothiazole-modified silica gel. Anal Bioanal Chem. 2003; 375: 5747.

    • Search Google Scholar
    • Export Citation
  • 7.

    Roldan PS Alcântara IL Padilha CCF Padilha PM . Determination of copper, iron, nickel and zinc in gasoline by FAAS after sorption and preconcentration on silica modified with 2-aminotiazole groups. Fuel. 2005; 84: 3059 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8.

    Alvarez P Blanco C Granda M . The adsorption of chromium (VI) from industrial wastewater by acid and base-activated lignocellulosic residues. J Hazard Mater. 2007; 144: 4005 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9.

    Tiravanti G Petruzzelli D Passino R . Pretreatment of tannery wastewaters by an ion exchange process for Cr(III) removal and recovery. Water Sci Technol. 1997; 36: 197207.

    • Search Google Scholar
    • Export Citation
  • 10.

    Torres JD Faria EA Prado AGS . Thermodynamic studies of the interaction at the solid/liquid interface between metal ions and cellulose modified with ethylenediamine. J Hazard Mater. 2006; 129: 23943 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11.

    Yu B Zhang Y Shukla A Shukla SS Dorris KL . The removal of heavy metal from aqueous solutions by sawdust adsorption—removal of copper. J Hazard Mater. 2000; 80: 3342 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12.

    Babel S Kurniawan TA . Low-cost adsorbents for heavy metals uptake from contaminated water: a review. J Hazard Mater. 2003; 97: 21943 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13.

    Deydier E Guilet R Sharrock P . Beneficial use of meat and bone meal combustion residue: “an efficient low cost material to remove lead from aqueous effluent”. J Hazard Mater. 2003; 101: 5564 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14.

    Sen Gupta S Bhattacharyya KG . Immobilization of Pb(II), Cd(II) and Ni(II) ions on kaolinite and montmorillonite surfaces from aqueous medium. J Environ Manag. 2008; 87: 4658 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 15.

    El-Hamouz A Hilal HS Nassar N Mardawi Z . Solid olive waste in environmental cleanup: oil recovery and carbon production for water purification. J Environ Manag. 2007; 84: 8392 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16.

    Tarley CRT Arruda MAZ . Biosorption of heavy metals using rice milling by-products. Characterisation and application for removal of metals from aqueous effluents. Chemosphere. 2004; 54: 98795 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 17.

    Ansari R Fahim NK . Application of polypyrrole coated on wood sawdust for removal of Cr(VI) ion from aqueous solutions. React Func Polym. 2007; 67: 36774 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18.

    Karthikeyan T Rajgopal S Miranda LR . Chromium(VI) adsorption from aqueous solution by Hevea Brasilinesis sawdust activated carbon. J Hazard Mater. 2005; 124: 1929 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19.

    Djeribi R Hamdaoui O . Sorption of copper(II) from aqueous solutions by cedar sawdust and crushed brick. Desalination. 2008; 225: 95112 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20.

    Larous S Meniai AH Lehocine MB . Experimental study of the removal of copper from aqueous solutions by adsorption using sawdust. Desalination. 2005; 185: 48390 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 21.

    Deepa KK Sathishkumar M Binupriya AR Murugesan GS Swaminathan K Yun SE . Sorption of Cr(VI) from dilute solutions and wastewater by live and pretreated biomass of Aspergillus flavus. Chemosphere. 2006; 62: 83340 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 22.

    Garg UK Kaur MP Garg VK Sud D . Removal of hexavalent chromium from aqueous solution by agricultural waste biomass. J Hazard Mater. 2007; 140: 608 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 23.

    Pandey AK Pandey SD Misra V Srimal AK . Removal of chromium and reduction of toxicity to Microtox system from tannery effluent by the use of calcium alginate beads containing humic acid. Chemosphere. 2003; 51: 32933 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 24.

    Hu J Lo IMC Chen G . Fast removal and recovery of Cr(VI) using surface-modified jacobsite (MnFe2O4) nanoparticles. Langmuir. 2005;21: 111739 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 25.

    American Society for Testing Materials—ASTM D4749-87 (1994) e1. Standard test method for performing the sieve analysis of coal and designating coal size. West Conshohocken, Pennsylvania, 1994.

    • Search Google Scholar
    • Export Citation
  • 26.

    prado AGS torres JD Faria EA Dias SCL . Comparative adsorption studies of indigo carmine dye on chitin and chitosan. J Colloid Interface Sci. 2004; 277: 437 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 27.

    Prado AGS Deoliviera E . The interaction at the solid/liquid interface of 2, 4-dichlorophenoxyacetic acid with silica modified by reaction with ammonia gas. J Colloid Interface Sci. 2005; 291: 538 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 28.

    Cestari AR Vieira EFS Mattos CRS . Thermodynamics of the Cu(II) adsorption on thin vanillin-modified chitosan membranes. J Chem Thermodyn. 2006; 38: 10929 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 29.

    Vieira EFS Cestari AR Santos EB Rezende CX . Measurement of cation binding to immobilized vanillin by isothermal calorimetry. J Colloid Interface Sci. 2006; 298: 748 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 30.

    Okuno Y Yokoyama T Yokoyama S Kamikado S Mashiko S . Theoretical study of benzonitrile clusters in the gas phase and their adsorption onto a Au(111) surface. J Am Chem Soc. 2002; 124: 721825 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 31.

    Rudzinski W Charmas R Piasecki W Thomas F Vilieras F Prelot B , et al. Calorimetric effects accompanying ion adsorption at the charged metal oxide/electrolyte interfaces: effects of oxide surface energetic heterogeneity. Langmuir. 1998; 14: 521025 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 32.

    Dos Anjos FSC Vieira EFS Cestari AR . Interaction of indigo carmine dye with chitosan evaluated by adsorption and thermochemical data. J Colloid Interface Sci. 2002; 253: 2436 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 33.

    Argun ME Dursun S Ozdemir C Karatas M . Heavy metal adsorption by modified oak sawdust: thermodynamics and kinetics. J Hazard Mater. 2007; 141: 7785 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 34.

    Aydin H Buluta Y Yerlikaya C . Removal of copper (II) from aqueous solution by adsorption onto low-cost adsorbents. J Environ Manag. 2008; 87: 3745 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 35.

    Trivedi P Axe L . Modeling Cd and Zn sorption to hydrous metal oxides. Environ Sci Technol. 2000; 34: 221523 .

  • 36.

    Alcantara EFC Faria EA Rodrigues DV Evangelista SM Deoliveira E Zara LF , et al. Modification of silica gel by attachment of 2-mercaptobenzimidazole for use in removing Hg(II) from aqueous media: a thermodynamic approach. J Colloid Interface Sci. 2007; 311: 17 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 37.

    Arakaki LNH Da Fonseca MG Da Silva EC Alves APM De Sousa KS Silva ALP . Extraction of Pb(II), Cd(II), and Hg(II) from aqueous solution by nitrogen and thiol functionality grafted to silica gel measured by calorimetry. Thermochim Acta. 2006; 450: 125 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 38.

    Vieira EFS Cestari AR Oliveira CS Lima PS Almeida LE . Thermodynamics of pyrimethamine and sulfadiazine binding to a chitosan derivative. Thermochim Acta. 2007; 459: 911 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 39.

    National Environment Comission—CONAMA. Resolution no. 357/2005. Brazilian Environment Ministry, Brasilia, Brazil, 2005 (in Portuguese).

    • Search Google Scholar
    • Export Citation

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

For subscription options, please visit the website of Springer.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Apr 2021 0 0 0
May 2021 5 0 0
Jun 2021 2 0 0
Jul 2021 3 0 0
Aug 2021 1 0 0
Sep 2021 3 0 0
Oct 2021 0 0 0