Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 101: Issue 1
Bi-component redox systems obtained from iridium or rhodium chlorides and molybdophosphoric heteropoly acid
Authors:
Lidia Kuznetsova Boreskov Institute of Catalysis SB RAS, Pr. Ak. Lavrentieva 5, Novosibirsk, 630 090 Russia

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Sergei Koscheev Boreskov Institute of Catalysis SB RAS, Pr. Ak. Lavrentieva 5, Novosibirsk, 630 090 Russia

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Nina Kuznetsova Boreskov Institute of Catalysis SB RAS, Pr. Ak. Lavrentieva 5, Novosibirsk, 630 090 Russia

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Ludmila Detusheva Boreskov Institute of Catalysis SB RAS, Pr. Ak. Lavrentieva 5, Novosibirsk, 630 090 Russia

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Pages:
1–12
Online Publication Date:
04 Jun 2010
Publication Date:
01 Oct 2010
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-010-0204-0
Keywords:
Catalysis; Oxidation; Ir(III) and Rh(III) complexes; Molybdophosphoric heteropoly acid; Benzene
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Abstract

An XP, IR and UV–VIS spectroscopy study was carried out to characterize the compositions of molybdophosphate heteropoly anions with Ir(III) or Rh(III) hydroxo–chloro complexes, such as Ir1.1Cl2.4OxHy·(PMo12O40)·16.0 H2O, where x is the number of oxygen atoms in the coordination sphere of iridium, and also mixed-valent species containing partially reduced and dehydrated heteropoly acid of suggested composition (Ir0, IrIII)n Clm Ox Hy (PMo12−pVIMopVO40−p/2) (on the average, n ≈ 1, m < 1, p ≥ 4). The mixed-valent Ir containing species showed stable activity in the gas-phase oxidation of benzene by O2–H2 mixture.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
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Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

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