RETRACTED ARTICLE: Effect of Gd2O3 over Ni/SiO2 on syngas production via methane autothermal reforming

Jian-Zhong Guo; Zhao-Yin Hou; Xiao-Ming Zheng

doi:10.1007/s11144-010-0210-2

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Reaction Kinetics, Mechanisms and Catalysis

Volume/Issue:: Volume 101: Issue 1

RETRACTED ARTICLE: Effect of Gd₂O₃ over Ni/SiO₂ on syngas production via methane autothermal reforming

Authors:

Jian-Zhong Guo

Jian-Zhong Guo Department of Chemistry, Zhejiang A & F University, Lin'an, Zhejiang, 311300, China

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Zhao-Yin Hou

Zhao-Yin Hou Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, xixi Campus, Hangzhou, Zhejiang, 310028, China

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, and

Xiao-Ming Zheng

Xiao-Ming Zheng Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, xixi Campus, Hangzhou, Zhejiang, 310028, China

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Pages:: 129–140

Online Publication Date:: 06 Jun 2010

Publication Date:: 01 Oct 2010

Article Category:: Research Article

DOI:: https://doi.org/10.1007/s11144-010-0210-2

Keywords:: Syngas; Ni catalyst; Rare earth oxide; Gd2O3; Methane

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Abstract

Gd₂O₃-promoted Ni/SiO₂ catalysts exhibited higher activity and selectivity than Ni/SiO₂ in methane autothermal reforming. The results of the temperature-programmed surface reaction of CH₄ indicated that Gd₂O₃ might enhance anti-carbon deposition properties. The reactivity of surface carbons showed that the presence of Gd₂O₃ reduced the formation of inactive carbons on Ni/SiO₂. Raman results suggested that the order of graphitization of deposited carbon decreases with the addition of Gd₂O₃.

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Reaction Kinetics, Mechanisms and Catalysis

Print ISSN:: 1878-5190

Online ISSN:: 1878-5204

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Reaction Kinetics, Mechanisms and Catalysis
Language	English
Size	B5
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ISSN	1878-5190 (Print)
ISSN	1878-5204 (Online)