Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 101: Issue 1
Kinetics of brilliant green fading in the presence of TX-100, DTAB and SDS
Authors: Babak Samiey1 and Mohammad Dargahi1
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  • 1 Department of Chemistry, Faculty of Science, University of Lorestan, 68137-17133 Khoramabad, Iran
Pages:
25–39
Online Publication Date:
04 Jun 2010
Publication Date:
01 Oct 2010
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-010-0208-9
Keywords:
Classical model; Brilliant green; Kinetics; Fading; Surfactant
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Abstract

The rate constant of alkaline fading of brilliant green (BG+) was measured in the presence of non ionic (TX-100), cationic (DTAB) and anionic (SDS) surfactants. This reaction was studied under pseudo first-order conditions at 283–303 K. The rate of reaction showed remarkable dependence on the electrical charge of the used surfactants. It was observed that the reaction rate constant increases in the presence of TX-100 and DTAB (catalytic effect) and decreases in the presence of SDS (inhibitory effect). Binding constants and the related thermodynamic parameters were obtained by the classical model. The results show that binding of BG+ to TX-100 is exothermic and binding of BG+ to DTAB and SDS is endothermic in the used concentration range of surfactants.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
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Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
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Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

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