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  • 1 Shandong Provincial Key Laboratory of Fine Chemicals, Shandong Institute of Light Industry, Jinan, Shandong 250353, China
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Abstract

The reaction of o-hydroxybenzyl alcohol with phenyl isocyanate has been investigated in different polar solvents with in situ FT-IR. The rate constants for the reactions of the phenolic hydroxyl group and the aliphatic hydroxyl group were calculated as k1 and k2, respectively. It is found that the phenolic hydroxyl group reacts more easily than the aliphatic hydroxyl group. It is also found that k1 increases with increasing solvent polarity, while the trend of k2 is the opposite. Moreover, the reaction kinetics is second-order with respect to toluene, butyl acetate, cyclohexanone and pyridine, but is first-order with respect to NMP and DMF without distinction for the two kinds of hydroxyl groups.

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  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)