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  • 1 School of Chemistry and Chemical Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, Jiangsu, People's Republic of China
  • | 2 School of Material Science and Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, Jiangsu, People's Republic of China
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Abstract

A novel one-pot catalytic synthesis of 5-acetylacenaphthene through the acylation of acenaphthene with acetyl chloride catalyzed by various Keggin type heteropoly acids (salts) was investigated. Pure 5-acetylacenaphthene was obtained and the structure of 5-acetylacenaphthene was identified by GC/MS, FT-IR and 1H NMR spectra. H3PW12O40 (PW) was found to be the most active catalyst in the acylation. The yield and the selectivity of 5-acetylacenaphthene were 51.2 and 83.4%, respectively. The effects of experimental parameters on the catalytic acylation reaction and the recycling performance of PW catalyst were studied. The PW catalyst shows good catalytic activity after running for five times. The facile product separation and the recycling performance of the PW catalyst is expected to contribute to the development of a clean and environmentally friendly strategy for the synthesis of 5-acetylacenaphthene.

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Manuscript submission: www.editorialmanager.com/reac

  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)