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  • 1 State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China lijb07@mails.tsinghua.edu.cn
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Abstract

The deactivation of alkali solid catalysts for the synthesis of glycerol carbonate from glycerol and dimethyl carbonate was investigated. Calcium oxide, calcium hydroxide and calcium methoxide were chosen as the representatives of the alkali solid catalysts. When the catalysts were recycled, the yield of glycerol carbonate decreased dramatically. The alkali solid catalyst was converted to the basic calcium carbonate Cax(OH)y(CO3)z, which was the cause of the decrease of glycerol carbonate yield. It was found that the chemical interactions of the alkali solid catalyst with glycerol and glycerol carbonate led to the formation of the basic calcium carbonate Cax(OH)y(CO3)z, for which the mechanism was proposed. Based on the deactivation mechanism, calcium diglyceroxide was adopted as a new catalyst for the transesterification of glycerol and dimethyl carbonate. Compared to calcium oxide, calcium hydroxide and calcium methoxide, calcium diglyceroxide showed excellent reusability for the transesterification of glycerol and dimethyl carbonate. For calcium oxide, calcium methoxide and calcium diglyceroxide, there were dissolution losses of the catalysts in the reaction medium. For calcium hydroxide, the catalyst dissolution loss in the reaction medium was nearly negligible. For calcium diglyceroxide, the dissolution of the catalyst in the reaction medium did not influence the yield of glycerol carbonate significantly.

  • 1. Behr, A, Enilting, J, Irawadi, K, Leschinski, J, Lindner, F 2008 Green Chem 10:1330 .

  • 2. Kovvali, AS, Sirkar, KK 2002 Ind Eng Chem Res 41:22872295 .

  • 3. Rousseau, J, Rousseau, C 2009 Tetrahedron 65:85718581 .

  • 4. Selva, M, Fabris, M 2009 Green Chem 11:11611172 .

  • 5. Ghandi, M, Mostashari, A, Karegar, M, Barzegar, MJ 2007 Am Oil Chem Soc 84:681685 .

  • 6. Rokicki, G, Rokoczy, P, Parzuchowski, P, Sobiecki, M 2005 Green Chem 7:529539 .

  • 7. Strain F (1948) US Patent 2,446,145.

  • 8. George, J, Patel, Y, Pillai, SM, Munshi, P 2009 J Molec Catal A Chem 304:17 .

  • 9. Kossev, KS, Koseva, NS, Troev, KD 2003 React Kinet Catal Lett 79:1118 .

  • 10. Clment, MJ, Corma, A, Frutos, PD, Iborra, S, Noy, M, Velty, A, Concepcion, P 2010 J Catal 269:140149 .

  • 11. Aresta, M, Dibenedetto, A, Nocito, F, Ferragina, C 2009 J Catal 268:106114 .

  • 12. Pelet, S, Yoo, JW, Mouloungui, Z 1999 J High Resol Chromatogr 22:276278 .

  • 13. Kim, SC, Kim, YH, Lee, H, Yoon, DY, Song, BK 2007 J Molec Catal B Enzym 49:7578 .

  • 14. Ochoa-Gomez, JR, Gomez-Jimenez-Aberasturi, O, Maestro-Madurga, B, Pesquera-Rodriguez, A, Ramirez-Lopez, C, Lorenzo-Ibarreta, L, Torrecilla-Soria, J, Villaran-Velasco, MC 2009 Appl Catal A Gen 366:315324 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 15. Takagaki, A, Iwatani, K, Nishimura, S, Ebitani, K 2010 Green Chem 12:578581 .

  • 16. Alvarez MG , Segarra AM, Contreras S, Sueiras JE, Medina F, Figueras F (2008) Chem Eng J. doi: .

  • 17. Kouzu, M, Kasuno, T, Tajika, M, Sugimoto, Y, Yamanaka, S, Hidaka, J 2008 Fuel 87:27982806 .

  • 18. Li, J, Wang, T 2010 Chem Eng Process 49:530535.

  • 19. Kouzu, M, Kasuno, T, Tajika, M, Sugimoto, Y, Yamanaka, S, Hidaka, J 2008 Appl Catal A Gen 334:357365 .

  • 20. Magniont, C, Escadeillas, G, Multon, CO, Caro, PD 2010 Cem Concr Res 40:10721080 .

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  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)