View More View Less
  • 1 College of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, People's Republic of China
  • | 2 College of Science, Hebei University of Engineering, Handan 056038, People's Republic of China
  • | 3 School of Material Science and Engineering, Shijiazhuang Tiedao University, Shijiazhuang 050043, People's Republic of China
  • | 4 College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050016, People's Republic of China
Restricted access

Abstract

Au/SiO2 catalysts were prepared by self-assembly technique and characterized by EDS, XRD, XPS, AAS and N2 adsorption/desorption. They were found to be very efficient catalysts for the selective oxidation of cyclohexane with air in the absence of any solvent or promoter. The influences of Au loading, reaction temperature, reaction pressure and reaction time on the catalytic activity were explored in detail. Under suitable reaction conditions, the conversion of cyclohexane and total selectivity of cyclohexanone and cyclohexanol were up to ∼10 and ∼92%, respectively.

  • 1. Hammer, B, Nørskov, JK 1995 Nature 376:238240 .

  • 2. Haruta, M, Yamada, N, Kobayashi, T, Iijima, S 1989 J Catal 115:301309 .

  • 3. Haruta, M 2003 Chem Record 3:7587 .

  • 4. Meyer, R, Lemire, C, Shaikhutdinov, SK, Freund, HJ 2004 Gold Bull 37:72124.

  • 5. Haruta, M 2003 Gold Bull 37:2736.

  • 6. Schuchardt U , Carvalho WA, Spinacé EV (1993) Synlett 10: 713718.

  • 7. Schuchardt, U, Cardoso, D, Sercheli, R, Pereira, R, Cruz, RS, Guerreiro, MC, Mandelli, D, Spinace, EV, Fires, EL 2001 Appl Catal A Gen 211:117 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Faith, WL, Keyes, DB, Clark, RL 1957 Industrial chemicals 2 Wiley New York.

  • 9. Musser MT (1987) In: Gerhartz W (ed) Encyclocarbons of industrial chemistry. VCH, Weinheim.

  • 10. , GM, Ji, D, Qian, G, Qi, YX, Wang, XL, Suo, JS 2005 Appl Catal A Gen 280:175180 .

  • 11. Zhao, R, Ji, D, , GM, Qian, G, Yan, L, Wang, XL, Suo, JS 2004 Chem Commun 7:904905 .

  • 12. , GM, Zhao, R, Qian, G, Qia, YX, Wang, XL, Suo, JS 2004 Catal Lett 97:115118 .

  • 13. Zhu, K, Hu, JC, Richards, R 2005 Catal Lett 100:195199 .

  • 14. Xu, YJ, Landon, P, Enache, D, Carley, AF, Roberts, MW, Hutchings, GJ 2005 Catal Lett 101:175179 .

  • 15. Xu, LX, He, CH, Zhu, MQ, Fang, S 2007 Catal Lett 114:202205 .

  • 16. Bamwenda, GR, Tsubota, S, Nakamura, T, Haruta, M 1997 Catal Lett 44:8387 .

  • 17. Hodge, NA, Kiely, CJ, Siddiqui, MRH, Hutchings, GJ, Pankhurst, QA, Wsgner, FE, Rajaram, RR, Golunski, SE 2002 Catal Today 72:133144 .

  • 18. Mallick, K, Witcomb, MJ, Scurrell, MS 2004 J Mol Catal A Chem 215:103106 .

  • 19. Riahi, G, Guillemot, D, Polisset-Thfoin, M, Khodadadi, AA, Fraissard, J 2002 Catal Today 72:115121 .

  • 20. Chen, W, Xiao, YH, Zhan, YY, Cai, GH, Wei, KM, Zheng, Q 2004 Spectrosc Spectr Anal 24:10961098 (in Chinese).

  • 21. Xu, LX, He, CH, Zhu, MQ, Wu, KJ, Lai, YL 2008 Catal Commun 9:816820 .

  • 22. Li, X, Ma, XC, Li, ST, Wen, SL, Lun, N 2004 J Mater Sci Eng 22:4851 (in Chinese).

  • 23. Kozlova, AP, Kozlov, AI, Sugiyama, S, Matsui, Y, Asakura, K, Iwasawa, Y 1999 J Catal 181:3748 .

  • 24. Bond, GC, Thompson, DT 1999 Catal Rev Sci Eng 41:319388 .

  • 25. Hashmi, ASK, Hutchings, GJ 2006 Angew Chem Int Ed 45:78967937 .

  • 26. Dobrosz, I, Jiratova, K, Pitchon, V, Rynkowski, JM 2005 J Mol Catal A Chem 234:187197 .

  • 27. Park, ED, Lee, JS 1999 J Catal 186:111 .

  • 28. Casaletto, MP, Longo, A, Venezia, AM, Martorana, A, Prestianni, A 2006 Appl Catal A Gen 302:309316 .

  • 29. Xue, W, Zhang, JC, Wang, YJ, Zhao, XQ 2005 Acta Pet Sinica 21:3743 (in Chinese).

  • 30. Xie J , Wang YJ, Li YT, Zhao XQ, Wei Y (2008) Gold 36 (in Chinese).

  • 31. Huang, G, Guo, YA, Zhou, H, Zhao, SK, Liu, SY, Wang, AP, Wei, JF 2007 J Mol Catal A Chem 273:144148 .

  • 32. Doron, A, Katz, E, Willner, I 1995 Langmuir 11:13131317 .

  • 33. Huang, XH, Huang, HZ, Wu, NZ, Hu, RS, Zhu, T, Liu, ZF 2000 Surf Sci 459:183190 .

  • 34. Liu, FK, Hsu, YT, Wu, CH 2005 J Chromatogr A 1083:205214 .

  • 35. Pan, BF, Gao, F, Ao, LM, Tian, HY, He, R, Cui, DX 2005 Colloids Surf A 259:8994 .

  • 36. Hu, RS, Liu, ST, Zhu, T, Liu, ZF 1999 Acta Phys-Chim Sin 15:961965 (in Chinese).

  • 37. Schubert, MM, Hackenberg, S, Veen, ACV, Muhler, M, Plzak, V, Behm, RJ 2001 J Catal 197:113122 .

  • 38. Haruta, M 2002 CATTECH 6:102115 .

  • 39. Castaño, P, Zepeda, TA, Pawelec, B, Makkee, M, Fierro, JLG 2009 J Catal 267:3039 .

  • 40. Sing, KSW, Everett, DH, Haul, RAW, Mosenu, L, Pierotti, RA, Rouquerol, J, Siemieniewska, T 1985 Pure & Appl Chem 57:603619 .

  • 41. Reddy, SS, Raju, BD, Padmasri, AH, Prakash, PKS, Rao, KSR 2009 Catal Today 141:6165 .

Manuscript submission: www.editorialmanager.com/reac

  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

For subscription options, please visit the website of Springer

Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)