View More View Less
  • 1 Hochiminh City University of Technology (HCMUT), Hochiminh city, Vietnam
  • | 2 Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology, AIST Tsukuba center 5, 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8565, Japan
Restricted access

Abstract

Li and Mn have been used as secondary additives in Rh–Fe/TiO2 (Rh catalyst, TiO2 support, and Fe promoter) for the synthesis of ethanol from syngas. Introducing Li or Mn in Rh–Fe/TiO2 slightly decreased the catalytic activity but improved the ethanol selectivity. Li or Mn-added Rh–Fe/TiO2 showed high ethanol yield at high reaction temperatures because the catalytic activity increased at high reaction temperatures while the ethanol selectivity was kept at a high level.

  • 1. Spivey, JJ, Egbebi, A 2007 Chem Soc Rev. 36:1514 .

  • 2. Subramani, V, Gangwal, SK 2008 Energy Fuel. 22:814 .

  • 3. Haider, MA, Gogate, MR, Davis, RJ 2009 J Catal. 261:9 .

  • 4. Yin, H, Ding, Y, Luo, H, Yan, L, Wang, T, Lin, L 2003 Energy Fuel. 17:1401 .

  • 5. Egbebi, A, Schwartz, V, Overbury, SH, Spivey, JJ 2010 Catal Today. 149:91 .

  • 6. Mei, D, Rousseau, R, Kathmann, SW, Glezakou, VA, Engelhard, MH, Jiang, W, Wang, C, Gerber, MA, White, JF, Stevens, DJ 2010 J Catal. 271:325 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7. Sun, X, Robert, GW 2003 Appl Catal A Gen. 247:133 .

  • 8. Liu, Y, Murata, K, Inaba, M, Takahara, I, Okabe, K 2010 J Japan Petro Instit. 53:153 .

  • 9. Okabe, K, Yamada, H, Hanaoka, T, Matsuzaki, T, Arakawa, H, Abe, Y 2001 Chem Lett. 30:904 .

  • 10. Pijolat, M, Perrichon, V 1985 Appl Catal. 13:321 .

  • 11. Bian, G, Fan, L, Fu, Y, Fujimoto, K 1998 Appl. Catal A. 170:255 .

  • 12. Bao, J, Sun, ZH, Fu, YL, Bian, GZ, Zhang, Y, Tsubaki, N 2009 Top Catal. 52:789 .

  • 13. Burch, R, Hayes, MJ 1997 J Catal. 165:249 .

  • 14. Hua, DY, An, CD, Rui, TK 1987 Appl Catal. 35:77 .

  • 15. Gogate, MR, Davis, RJ 2009 ChemCatChem. 1:295 .

  • 16. Xu, BQ, Sun, KQ, Zhu, QM, Sachtler, WMH 2000 Catal Today. 63:453 .

  • 17. Au, CT, Wang, HY 1997 J Catal. 167:337 .

  • 18. Burch, R, Petch, MI 1992 Appl Catal A. 88:39 .

  • 19. Jiang, D, Ding, Y, Pan, Z, Chen, W, Luo, H 2008 Catal Lett. 121:241 .

  • 20. Garten, LG, Ollis, DF 1974 J Catal. 35:232 .

  • 21. Guglielminotti, E, Pinna, F, Rigoni, M, Strukul, G, Zanderighi, L 1995 J Mol Catal A Chem. 103:105 .

  • 22. Orita, H, Naito, S, Tamaru, K 1983 J Chem Soc Chem Commun. 18:993994 .

  • 23. Liu, Y, Hayakawa, T, Suzuki, K, Hamakawa, S, Tsunoda, T, Ishii, T, Kumagai, M 2002 Appl Catal A Gen. 223:137 .

  • 24. Liu, Y, Hayakawa, T, Tsunoda, T, Suzuki, K, Hamakawa, S, Murata, K, Shiozaki, R, Ishii, T, Kumagai, M 2003 Top Catal. 22:205 .

  • 25. Liu, Y, Hayakawa, T, Ishii, T, Kumagai, M, Yasuda, H, Suzuki, K, Hamakawa, S, Murata, K 2001 Appl Catal A Gen. 210:301 .

  • 26. Wang, Y, Luo, H, Liang, D, Bao, X 2000 J Catal. 196:45 .

  • 27. Chuang, SSC, Stevens, RW, Khatri, R 2005 Top Catal. 32:225 .