Authors:
Zhiqiang Wang Research Institute of Fine Chemical Engineering, Henan University, Kaifeng 475004, Henan, China

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Zhanwei Bu Research Institute of Fine Chemical Engineering, Henan University, Kaifeng 475004, Henan, China

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Tiegang Ren Research Institute of Fine Chemical Engineering, Henan University, Kaifeng 475004, Henan, China

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Tingting Cao Research Institute of Fine Chemical Engineering, Henan University, Kaifeng 475004, Henan, China

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Lirong Yang Research Institute of Fine Chemical Engineering, Henan University, Kaifeng 475004, Henan, China

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Abstract

The mechanism of the cycloaddition of CO2 with propylene oxide to afford propylene carbonate catalyzed by a highly active trans-dichlorotetrapyridineruthenium [trans-Ru(py)4Cl2] complex and tetrabutylammonium chloride (TBAC) has been studied by means of electrospray ionization mass spectrometry (ESI–MS), structural characterization of trans-Ru(py)4Cl2, catalyst activity tests and so on. Further experiments demonstrated that the tributylamine formed in situ was involved in the catalysis and that addition of butyl chloride to re-convert the tributylamine into TBAC resulted in the inhibition of the reaction. The mechanistic study explains the reported early experimental observations well and provides a clear profile for the cycloaddition of carbon dioxide with propylene oxide using trans-Ru(py)4Cl2 as catalyst. The mechanism also fully explains the role of the TBAC by providing a role for the in situ generated tributylamine in activating the carbon dioxide.

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
1
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)