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  • 1 Department of Studies in Chemistry, Central College Campus, Bangalore University, Bangalore 560 001, India
  • | 2 Siddaganga Institute of Technology, Tumkur, Karnataka, 572 103, India
  • | 3 National Centre for Catalysis Research, IIT Madras, Chennai 600 036, India
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Abstract

Hydrogenation of various nitroarenes by a polymer-supported palladium-imidazole complex at ambient conditions was investigated. The effect of various substituents upon the rate of hydrogenation of nitrobenzene was studied. The rate of para-substituted nitrobenzene hydrogenation was related to the corresponding Hammett substituent constant. The kinetics of hydrogenation and the reusability of the catalyst were also studied.

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