Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 103: Issue 2
Study on the influence of substituents upon the hydrogenation of nitrobenzene using a polymer-supported palladium-imidazole complex catalyst
Authors: V. Udayakumar 1 , S. Alexander 1 , V. Gayathri 1 , Shivakumaraiah 2 , and B. Viswanathan 3
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  • 1 Department of Studies in Chemistry, Central College Campus, Bangalore University, Bangalore 560 001, India
  • 2 Siddaganga Institute of Technology, Tumkur, Karnataka, 572 103, India
  • 3 National Centre for Catalysis Research, IIT Madras, Chennai 600 036, India
DOI:
https://doi.org/10.1007/s11144-011-0308-1
Page Count:
341–352
Publication Date:
01 Aug 2011
Online Publication Date:
05 Apr 2011
Article Category:
Research Article
Restricted access

Abstract

Hydrogenation of various nitroarenes by a polymer-supported palladium-imidazole complex at ambient conditions was investigated. The effect of various substituents upon the rate of hydrogenation of nitrobenzene was studied. The rate of para-substituted nitrobenzene hydrogenation was related to the corresponding Hammett substituent constant. The kinetics of hydrogenation and the reusability of the catalyst were also studied.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204
Keywords:
Recoverable catalyst; Polymer-supported catalyst; Substituted nitrobenzene; Catalytic hydrogenation; Hammett's substituent constant

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