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  • 1 Laboratoire De Chimie Des Matériaux et Catalyse, Département de Chimie, Faculté des Sciences de Tunis, Campus Universitaire de Tunis El Manar, 2092, Tunis, Tunisie
  • | 2 Unité de Catalyse et de Chimie du Solide, UMR CNRS 8181 USTL—Bâtiment C3, 59655, Villeneuve d'Ascq Cedex, France
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Abstract

The role of palladium precursors and the preparation route in the catalytic properties of Pd/Al2O3-ZrO2 catalysts toward methane oxidation was investigated in this paper. The palladium precursors were Pd acetylacetonate Pd(C5H7O2)2 and palladium nitrate Pd(NO3)2. Catalysts were prepared by using either sol-gel or wet impregnation. All catalysts were characterized by N2 physiorption, H2 chemisorption, H2 TPR, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The obtained results suggested that the use of different palladium precursors and preparation routes played an important role in the properties of the catalysts. The use of palladium acetylacetonate as precursor for the impregnation method generated more active catalysts. However, sol-gel prepared catalyst presented better textural properties with moderate catalytic activities.

  • 1.

    Simplício, LMT, Brandão, ST, Sales, EA, Lietti, L, Bozon-Verduraz, F (2006) Appl Catal B: Environ. 63:9 .

  • 2.

    Ciuparu, D, Lyubovsky, MR, Altman, E, Pfefferle, LD, Datye, A (2002) Catal Rev. 44:593 .

  • 3.

    Geus, JW JC Van Giezen 1999 Catal Today. 47:169 .

  • 4.

    Forzatti, P, Groppi, G (1999) Catal Today. 54:165 .

  • 5.

    Centi, G (2001) J Mol Catal A. 173:287 .

  • 6.

    Gélin, P, Primet, M (2002) Appl Catal B: Environ. 39 1 1 .

  • 7.

    Choudhary, TV, Banerjee, S, Choudhary, VR (2002) Appl Catal A. 234:1 .

  • 8.

    Forzatti, P (2003) Catal Today. 83:3 .

  • 9.

    Kuper, WJ, Blaauw, M F Van Der Berg Graaf, GH (1999) Catal Today. 47:377 .

  • 10.

    Prasad, R, Kennedy, LA, Ruckenstein, E (1984) Catal Rev Sci Eng. 26 1 1 .

  • 11.

    Briot, P, Primet, M (1991) Appl Catal. 68:301 .

  • 12.

    Baldwin, TR, Burch, R (1990) Appl Catal. 66:337 .

  • 13.

    Burch, R, Loader, PK, Urbano, FJ (1996) Catal Today. 27:243 .

  • 14.

    Veser G , Ziauddin M, Schmidt LD (1999) Catal Today 47: 219.

  • 15.

    Thevenin, PO, Pocoroba, E, Pettersson, LJ, Karhu, H, Vayrynen, IJ, Jaras, SG (2002) J Catal. 207:139 .

  • 16.

    Kucharczyk, B, Tylus, W, Kepinski, L (2004) Appl Catal B. 149:27.

  • 17.

    Debasish, S, Deepak, M, Sambarta, R, Santanu, B, Sukumar, A, Niren, M (2007) Ceram Int. 33:1275 .

  • 18.

    Becher, PF, Alexander, BK, Bleier, A, Baters, BS, Warwick, WH (1993) J Am Ceram Soc. 76:657 .

  • 19.

    Schmal, M, Souza, MMVM, Aranda, DAG, Perez, CAC (2001) Stud Surf Sci Catal. 132:695 .

  • 20.

    Dalla-Betta RA , Tsurumi K, Shoji T, Garten RL (1995) US Patent 5, 260.

  • 21.

    Oh, SeH, Mitchell, PJ, Stiewert, RM (1995) J Catal. 132:287 .

  • 22.

    Burch, R, Urbano, FJ, Loader, PK (1995) Appl Catal A. 123:173 .

  • 23.

    Fessi, S, Ghorbel, A, Rives, A, Hubaut, R (2000) Stud Surf Sci Catal. 130:3795 .

  • 24.

    Demoulin, O, Le Clef, B, Navez, M, Ruiz, P (2008) Appl Catal A: General. 344:1 .

  • 25.

    Guo, Y, Lu, G, Zhang, Zh, Jiang, L, Wang, X, Li, Sh, Zhang, B, Niu, J (2007) Catal Today. 126:441 .

  • 26.

    Amairia, C, Fessi, S, Ghorbel, A (2010) J Sol-Gel Sci Technol. 54:29 .

  • 27.

    Baylet, A, Royer, S, Marécot, P, Tatibouët, JM, Duprez, D (2008) Appl Catal B: Environ. 81:88 .

  • 28.

    Monteiro, RS, Dieguez, LC, Schmal, M (2001) Catal Today. 65:77 .

  • 29.

    Amairia, C, Fessi, S, Ghorbel, A (2009) Sol-Gel Sci Technol. 52:260 .

  • 30.

    Cubeiro, ML, Fierro, JLG (1998) Appl Catal A. 168:307 .

  • 31.

    Iwasa, N, Kudo, N, Takahashi, H, Masuda, S, Takazawa, N (1993) Catal Lett. 19:211 .

  • 32.

    Hong, ChT, Yeh, ChT, Yu, FH (1989) Appl Catal. 48:385 .

  • 33.

    Shen, WJ, Okumura, M, Matsumura, Y, Haruta, M (2001) Appl Catal A: General. 213:225 .

  • 34.

    Lin, W, Zhu, YX, Wu, NZ, Xie, YC, Murwani, I, Kemnitz, E (2004) Appl Catal B. 50:59 .

Manuscript submission: www.editorialmanager.com/reac

  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)