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  • 1 Chemistry Department, University of the Free State, P.O. Box 339, Bloemfontein 9300, Republic of South Africa
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Abstract

The kinetics of the oxidation of formaldehyde by octacyanomolybdate(V) ions has been studied in aqueous alkaline medium. A formaldehyde-dependent and -independent reaction has been observed. The HCHO-dependent reaction displays first order kinetics in [Mo(CN)83−], [HCHO], [OH] and alkali metal ion catalysis was observed. The rate law is consistent with: Activation parameters for both the formaldehyde-dependent and -independent reaction have been obtained. The activation parameters for the HCHO-independent reaction provide evidence for the identification of the reaction. A reaction mechanism is proposed.

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