Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 104: Issue 1
Doped Keggin heteropolyacids as catalysts in sulfide oxidation
Authors:
Valeria Palermo Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J. Ronco” (CINDECA), CCT-LaPlata-CONICET, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 Nº 257 (B1900AJK), La Plata, Argentina

Search for other papers by Valeria Palermo in
Current site
Google Scholar
PubMed Close
,
Ángel G. Sathicq Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J. Ronco” (CINDECA), CCT-LaPlata-CONICET, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 Nº 257 (B1900AJK), La Plata, Argentina

Search for other papers by Ángel G. Sathicq in
Current site
Google Scholar
PubMed Close
,
Patricia G. Vázquez Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J. Ronco” (CINDECA), CCT-LaPlata-CONICET, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 Nº 257 (B1900AJK), La Plata, Argentina

Search for other papers by Patricia G. Vázquez in
Current site
Google Scholar
PubMed Close
,
Horacio J. Thomas Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J. Ronco” (CINDECA), CCT-LaPlata-CONICET, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 Nº 257 (B1900AJK), La Plata, Argentina

Search for other papers by Horacio J. Thomas in
Current site
Google Scholar
PubMed Close
, and
Gustavo P. Romanelli Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J. Ronco” (CINDECA), CCT-LaPlata-CONICET, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 Nº 257 (B1900AJK), La Plata, Argentina

Search for other papers by Gustavo P. Romanelli in
Current site
Google Scholar
PubMed Close
Pages:
181–195
Online Publication Date:
25 Jun 2011
Publication Date:
01 Oct 2011
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-011-0341-0
Keywords:
Doped Keggin heteropolyacids; Sulfide oxidation; Bulk and supported catalysts; Sulfoxides; Sulfones
Restricted access

Abstract

In this research, we report the preparation of doped PMo Keggin heteropolyacids where Mo is partially replaced by V, Bi, and Bi–V. These catalysts were characterized by means of ICP-AES analysis, 31P-NMR, UV–visible spectra, FT-IR spectra, thermal analysis, and textural properties. In addition, the activities of the synthesized catalysts were evaluated in the selective oxidation of sulfides to sulfoxides/sulfones. The incorporation of V, Bi and Bi–V into the structure of H3PMo12O40 increases the catalytic activity. The two most active catalysts, those with V and V–Bi were supported on aminopropyl-functionalized silica (SiO2NH2) and they were found to be and efficient heterogeneous catalysts for the selective oxidation of diphenylsulfide to the corresponding sulfoxide/sulfone.

  • 1.

    Park, D, Park, P, Bang, Y, Song, I (2010) Appl Catal A 373:201–207 .

  • 2.

    Romanelli, G, Autino, J (2009) Mini Rev Org Chem 6:359–366 .

  • 3.

    Bennardi, D, Romanelli, G, Autino, J, Pizzio, L, Vázquez, P, Cáceres, C, Blanco, M (2010) React Kinet Mech Catal 100:165–174.

  • 4.

    Romanelli, G, Autino, P, Vázquez, P, Pizzio, L, Blanco, M, Cáceres, C (2003) Appl Catal A 352:208–213.

  • 5.

    Villabrille, P, Romanelli, G, Quaranta, N, Vázquez, P (2010) Appl Catal B 96:379–386 .

  • 6.

    Sambeth, J, Romanelli, G, Autino, J, Thomas, H, Baronetti, G (2010) Appl Catal A 378:114–118 .

  • 7.

    Tundo, P, Romanelli, G, Vázquez, P, Aricó, F (2010) Catal Commun 11:1181–1184 .

  • 8.

    Tundo, P, Romanelli, G, Vázquez, P, Loris, A, Aricó, F (2008) Synlett 7:967–970 .

  • 9.

    Villabrille, P, Romanelli, G, Vázquez, P, Cáceres, C (2008) Appl Catal A 334:374–380 .

  • 10.

    Rao, P, Venkateswara Rao, K, Sai Prasad, P, Lingaiah, N (2010) Catal Commun 11:547–550 .

  • 11.

    Kende, A, Ebertino, F (1984) Tetrahedron Lett 25:923–926 .

  • 12.

    El Ali, B, El-Ghanam, A, Fettouhi, M (2001) J Mol Catal A 165:283–289 .

  • 13.

    Seki, Y, Mizuno, K, Misono, M (2000) Appl Catal A 194:13–20 .

  • 14.

    Trost, B (1978) Chem Rev 78:363–382 .

  • 15.

    Carreno, M (1995) Chem Rev 95:1717–1760 .

  • 16.

    Karami, B, Ghoreishi-Nezhad, M, Clark, J (2005) Org Lett 8:625–628 .

  • 17.

    Ogura, K, Yahata, N, Fujimori, T, Fujita, M (1990) Tetrahedron Lett 31:4621–4624 .

  • 18.

    Ma, Y, Liu, R, Gong, X, Li, Z, Huang, Q, Wang, H, Song, G (2006) J Agric Food Chem 54:7724–7728 .

  • 19.

    Friedrich, M, Meichle, W, Bernhard, H, Rihs, G, Otto, H (1996) Archiv der Pharmazie 329:361–370 .

  • 20.

    Barrett A , Carr R, Attwood S, Richardson G, Walshe N (1986) J Org Chem 51: 4840–4856.

  • 21.

    Varma, R, Sain, R, Meshram, H (1997) Tetrahedron Lett 8:625–628 and references.

  • 22.

    Tajbakhsh, M, Hosseinzadeh, R, Shakoori, A (2004) Tetrahedron Lett 45:1889–1893 .

  • 23.

    Barton, D, Li, W (1998) Tetrahedron Lett 39:7075–7078 .

  • 24.

    Iwahana, T, Sakaguchi, S, Ishii, Y (1998) Tetrahedron Lett 39:9059–9062 .

  • 25.

    Bonadies, F F De Angelis Locati, L, Scettri, A (1996) Tetrahedron Lett 37:7129–7130 .

  • 26.

    Kaczorowska, K, Kolarska, Z, Mitka, K, Kowalski, P (2005) Tetrahedron 61:8315–8327 .

  • 27.

    Villabrille, P, Romanelli, G, Vázquez, P, Cáceres, C (2004) Appl Catal A 270:101–111 .

  • 28.

    Tarlani, A, Abedini, M, Nemati, A, Khabaz, M, Amini, M (2006) J Colloid Interface Sci 303:32–38 .

  • 29.

    Barteau, K, Lyons, J, Song, I, Barteau, M (2006) Top Catal 41:55–62 .

  • 30.

    Villabrille, P, Romanelli, G, Gassa, L, Vázquez, P, Cáceres, C (2007) Appl Catal A 324:69–76 .

  • 31.

    Vázquez, P, Blanco, M, Cáceres, C (1999) Catal Lett 60:205–215 .

  • 32.

    Vázquez, P, Pizzio, L, Cáceres, C, Blanco, M, Thomas, H, Alesso, E, Finkielsztein, L, Lantaño, B, Moltrasio, G, Aguirre, J (2000) J Mol Catal A 161:223–232 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 33.

    Pizzio, L, Romanelli, G, Vázquez, P, Autino, J, Blanco, M, Cáceres, C (2006) Appl Catal A 308:153–160 .

  • 34.

    Casarini, D, Centi, G, Jiro, P, Lena, V, Tvaruzkova, Z (1993) J Catal 143:325–344 .

  • 35.

    Palermo, V, Vázquez, P, Romanelli, G (2009) Phosphorus Sulfur Silicon Relat Elem 12:3258–3268 .

  • Collapse
  • Expand
Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

To see the editorial board, please visit the website of Springer Nature.

Manuscript submission: www.editorialmanager.com/reac

For subscription options, please visit the website of Springer Nature.

Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Mar 2024 40 1 0
Apr 2024 18 0 0
May 2024 17 0 0
Jun 2024 4 0 0
Jul 2024 18 0 0
Aug 2024 47 0 0
Sep 2024 3 0 0