View More View Less
  • 1 Department of Chemistry, University of Alzahra, P.O. Box 1993891176, Vanak, Tehran, Iran
Restricted access

Cross Mark

Abstract

Vanadium complexes of N-salicylidene-l-histidine immobilized on Al-MCM-41 designated as VO(Sal-His)/Al-MCM-41, were prepared and characterized by X-ray powder diffraction (XRD), FT-IR, nitrogen adsorption–desorption and chemical analysis techniques. VO(Sal-His)/Al-MCM-41 was found to catalyze the epoxidation of trans-2-hexen-1-ol, cinnamyl alcohol and geraniol with tert-butyl hydroperoxide (TBHP). The successful catalytic behavior of VO(Sal-His)/Al-MCM-41 with 99% conversion and excellent selectivity toward the corresponding epoxides is described herein.

  • 1.

    Shilov, AE, Shulpin, GB (1997) Chem Rev 97:28792932 .

  • 2.

    Bregeault JM (2003) Dalton Trans: 32893302.

  • 3.

    Gamez, P, Aubel, PG, Driessen, WL, Reedijk, J (2001) Chem Soc Rev 30:376385 .

  • 4.

    Lightenbarg, AGJ, Hage, R, Feringa, BL (2003) Coord Chem Rev 237:89101 .

  • 5.

    PR Ortiz de Montellano (ed) (1995) Cytochrome P450: structure, mechanisms and biochemistry 2 Plenum Press New York.

  • 6.

    Klinmann, JP (1996) Chem Rev 96:25412561 .

  • 7.

    Solomon, EI, Sundaram, UM, Machonkin, TE (1996) Chem Rev 96:25632606 .

  • 8.

    Rehder, D (2008)Bioinorganic vanadium chemistry John wiley sons & Ltd Press Chichester 105128 .

  • 9.

    Rehder, D (2003) Inorg Chem Commun 6:604617 .

  • 10.

    Thomson, KH, Mcneill, JH, Orvige, C (1999) Chem Rev 99:25612571 .

  • 11.

    Dembitsky, VM (2003) Tetrahedron 59:47014720 .

  • 12.

    Rehder, D (2008)Bioinorganic vanadium chemistry John wiley & sons Ltd Chichester 1353 .

  • 13.

    Canali, L, Sherrington, DC (1999) Chem Soc Rev 28:8593 .

  • 14.

    Kojima, M, Taguchi, H, Tsuchimoto, M, Nakajima, K (2003) Coord Chem Rev 237:183196 .

  • 15.

    Lane, BS, Burgress, K (2003) Chem Rev 103:24572473 .

  • 16.

    Gupta, KC, Sutar, AK (2008) Coord Chem Rev 252:14201450 .

  • 17.

    Boghaei, DM, Mohebi, S (2002) J Mol Catal A 179:4151 .

  • 18.

    Kwiatkowski, E, Romanowski, G, Nowicki, W, Kwiatkowski, M, Suwinska, K (2003) Polyhedron 22:10091018 .

  • 19.

    Ando, R, Inden, H, Sugino, M, Ono, H, Sakaeda, D, Yagyu, T, Maeda, M (2004) Inorg Chim Acta 357:13371344 .

  • 20.

    Kwiatkowski, E, Romanowski, G, Nowicki, W, Kwiatkowski, M, Suwinska, K (2007) Polyhedron 26:25592568 .

  • 21.

    Rayati, S, Sadeghzadeh, N, Khavasi, HR (2007) Inorg Chem Commun 10:15451548 .

  • 22.

    Romanowski, G, Kwiatkowski, E, Nowicki, W, Kwiatkowski, M, Lis, T (2008) Polyhedron 27:16011609 .

  • 23.

    Rayati, S, Koliaei, M, Ashouri, F, Mohebbi, S, Wojtczak, A, Kozakiewicz, A (2008) Appl Catal A 346:6571 .

  • 24.

    Cordelle, C, Agustin, D, Daran, JC, Poli, R (2010) Inorg Chim Acta 304:144149 .

  • 25.

    Yaul, AR, Pethe, GB, Aswar, AS (2010) Russ J Coord Chem 36:254258 .

  • 26.

    Sharpless, KB, Verhoven, TR (1979) Aldrichim Acta 12:6374.

  • 27.

    Maurya, MR, Chandrakar, AK, Chand, S (2007) J Mol Catal A 270:225235 .

  • 28.

    Maurya, MR, Chandrakar, AK, Chand, S (2007) J Mol Catal A 274:192201 .

  • 29.

    Gupta, KC, Sutar, AK, lin, C (2009) Coord Chem Rev 253:19261946 .

  • 30.

    Yang, Y, Zhang, Y, Hao, S, Guan, J, Ding, H, Shang, F, Qiu, P, Kan, Q (2010) Appl Catal A 381:274281 .

  • 31.

    Farzaneh, F, Zamanifar, E, Williams, CD (2004) J Mol Catal A 218:203209 .

  • 32.

    Zanjanchi, MA, Sh, Asgari (2004) Solid State Ionics 171:277282 .

  • 33.

    Pessoa, JC, Cavaco, I, Correia, I, Duarte, MT, Gillard, RD, Henriques, RT, Higes, FJ, Madeira, C, Tomaz, I (1999) Inorg Chim Acta 293:111 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 34.

    Lynch J (2001) Physico-chemical analysis of industrial catalysts. Technip ed., Paris.

  • 35.

    Selvaraj, M, Pandurangan, A, Seshadri, KS, Sinha, PK, Krishnasamy, V, Lal, KB (2003) J Mol Catal A 192:153170 .

  • 36.

    Kozlov, A, Asakura, K, Iwasawa, Y (1998) Micropor Mesopor Mater 21:571579 .

  • 37.

    Pereira, C, Silva, AR, Carvalho, AP, Pires, J, Freire, C (2008) J Mol Catal A 283:414.

  • 38.

    Jarrais, B, Pereira, C, Silva, AR, Carvalho, AP, Pires, J, Freire, C (2009) Polyhedron 28:9941000 .