Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 104: Issue 1
12-Tungstophosphoric acid supported on nano sized MCM-41 as an efficient and reusable solid acid catalyst for the three-component imino Diels–Alder reaction
Authors:
Mohammad Abdollahi-Alibeik Department of Chemistry, Yazd University, 89195-741, Yazd, Iran

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and
Marjan Pouriayevali Department of Chemistry, Yazd University, 89195-741, Yazd, Iran

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Pages:
235–248
Online Publication Date:
24 Jun 2011
Publication Date:
01 Oct 2011
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-011-0345-9
Keywords:
12-Tungstophosphoric acid; Imino Diels–Alder; Tetrahydroquinoline; Heteropoly acid; Nano sized MCM-41
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Abstract

One pot three-component imino Diels–Alder reactions of various types of aldehydes, aniline and dihydropyrane were studied in the presence of nano sized MCM-41 supported 12-tungstophosphoric acid (TPA) as solid acid catalyst. MCM-41 as solid support was synthesized in nano size and the catalysts with different loading amounts of TPA (5–30 wt%) were prepared and characterized by XRD, FT-IR and SEM techniques. The results confirm a good dispersion of the heteropoly acid on the solid supports and based on the experimental results, the catalyst with 10 wt% heteropoly acid shows the best catalytic activity using 0.5 mol% heteropoly acid relative to the aldehyde. The recovery experiments show that the catalyst is reusable after calcination without significant loss in its activity.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

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