Authors:
Mohammad Saleh Ghodrati Chemical Engineering Faculty, Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran
Reactor and Catalysis Research Center (RCRC), Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran

Search for other papers by Mohammad Saleh Ghodrati in
Current site
Google Scholar
PubMed
Close
,
Mohammad Haghighi Chemical Engineering Faculty, Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran
Reactor and Catalysis Research Center (RCRC), Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran
Nanostructure Material Research Center (NMRC), Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran

Search for other papers by Mohammad Haghighi in
Current site
Google Scholar
PubMed
Close
,
Jafar Sadegh Soltan Mohamdzadeh Chemical Engineering Faculty, Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran
Reactor and Catalysis Research Center (RCRC), Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran
Department of Chemical Engineering, University of Saskatchewan, 57 Campus Drive, Saskatoon, SK, S7N 5A9, Canada

Search for other papers by Jafar Sadegh Soltan Mohamdzadeh in
Current site
Google Scholar
PubMed
Close
,
Behzad Pourabas Nanostructure Material Research Center (NMRC), Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran

Search for other papers by Behzad Pourabas in
Current site
Google Scholar
PubMed
Close
, and
Ehsan Pipelzadeh Chemical Engineering Faculty, Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran
Reactor and Catalysis Research Center (RCRC), Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran
Nanostructure Material Research Center (NMRC), Sahand University of Technology, Sahand New Town, P. O. Box 51335-1996, Tabriz, Iran

Search for other papers by Ehsan Pipelzadeh in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract

Ultrasound energy has been successfully employed to synthesize CdSe/TiO2 nanocatalysts for the photocatalytic degradation of phenol under solar light irradiation. The photocatalytic performance test was carried out using TiO2 as well as synthesized CdSe/TiO2 nanocatalysts. Nanocatalyst characterization was accomplished using XRD, SEM, FTIR, BET and UV–vis spectroscopy. It was shown that the synthesized nanocatalysts have crystal characteristics and are in nano-scale size range. The coupled nanocatalyst has shown a shift in the absorption spectrum from the UV range to the visible range. The results of photocatalytic tests showed that the CdSe/TiO2 coupled nanocatalyst could remove phenol from wastewater under solar light irradiation, while TiO2 did not have enough activity in this process. It is also shown that the CdSe nanoparticles act as photosensitizers, not only extending the spectral response of TiO2 to the visible region but also reducing the electron–hole recombination. Furthermore, the CdSe/TiO2 synthesized samples provided more photomineralization efficiency than that of TiO2 in terms of total organic carbon analysis.

  • 1.

    Zhang, J-C, Gao, L-L, Cao, W-L (2003)A study on the preparation and photocatalytic properties of TiO2–SiO2 nanocomposite photocatalyst by supercritical fluid drying. Chin J Inorg Chem 19:934940.

    • Search Google Scholar
    • Export Citation
  • 2.

    Ksibi, M, Zemzemi, A, Boukchina, R (2003)Photocatalytic degradability of substituted phenols over UV irradiated TiO2. J Photochem Photobiol A 159 1 6170 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3.

    Guo, Z, Ma, R, Li, G (2006)Degradation of phenol by nanomaterial TiO2 in wastewater. Chem Eng J 119 1 5559 .

  • 4.

    Han, W, Zhu, W, Zhang, P, Zhang, Y, Li, L (2004)Photocatalytic degradation of phenols in aqueous solution under irradiation of 254 and 185 nm UV light. Catal Today 90 3–4 319324 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5.

    Wei, T-Y, Wan, C-c (1992)Kinetics of photocatalytic oxidation of phenol on TiO2 surface. J Photochem Photobiol A 69 2 241249 .

  • 6.

    Ho, W, Yu, JC (2006)Sonochemical synthesis and visible light photocatalytic behavior of CdSe and CdSe/TiO2 nanoparticles. J Mol Catal A 247 1–2 268274.

    • Search Google Scholar
    • Export Citation
  • 7.

    Qi, X-H, Wang, Z-H, Zhuang, Y-Y, Yu, Y, Li, J-l (2005)Study on the photocatalysis performance and degradation kinetics of X-3B over modified titanium dioxide. J Hazard Mater 118 1–3 219225 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8.

    Szabó-Bárdos, E, Pétervári, E, El-Zein, V, Horváth, A (2006)Photocatalytic decomposition of aspartic acid over bare and silver deposited TiO2. J Photochem Photobiol A 184 1–2 221227 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9.

    Yan, X, He, J, Evans, DG, Zhu, Y, Duan, X (2004)Preparation, characterization and photocatalytic activity of TiO2 formed from a mesoporous precursor. J Porous Mater 11 3 131140 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10.

    Khodja, AA, Sehili, T, Pilichowski, J-F, Boule, P (2001)Photocatalytic degradation of 2-phenylphenol on TiO2 and ZnO in aqueous suspensions. J Photochem Photobiol A 141 2–3 231239 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11.

    Ku, Y, Leu, R-M, Lee, K-C (1996)Decomposition of 2-chlorophenol in aqueous solution by UV irradiation with the presence of titanium dioxide. Water Res 30 11 25692578 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12.

    Theurich, J, Lindner, M, Bahnemann, DW (1996)Photocatalytic degradation of 4-chlorophenol in aerated aqueous titanium dioxide suspension: a kinetic and mechanistic study. Langmuir 12:63686376 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13.

    Bacsa, RR, Kiwi, J (1998)Effect of rutile phase on the photocatalytic properties of nanocrystalline titania during the degradation of p-coumaric acid. Appl Catal B 16 1 1929 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14.

    Mane, RS, Roh, SJ, Joo, O-S, Lokhande, CD, Han, S-H (2005)Improved performance of dense TiO2/CdSe coupled thin films by low temperature process. Electrochim Acta 50 12 24532459 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 15.

    Lo, S-C, Lin, C-F, Wu, C-H, Hsieh, P-H (2004)Capability of coupled CdSe/TiO2 for photocatalytic degradation of 4-chlorophenol. J Hazard Mater 114 1–3 183190 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16.

    Linsebigler, AL, Lu, G, Yates, JT (1995)Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results. Chem Rev 95 3 735758 .

  • 17.

    Ding, Z, Lu, GQ, Greenfield, PF (2000)Role of the crystallite phase of TiO2 in heterogeneous photocatalysis for phenol oxidation in water. J Phys Chem B 104 19 48154820 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18.

    Kolen'ko, YV, Garshev, AV, Churagulov, BR, Boujday, S, Portes, P, Colbeau-Justin, C (2005)Photocatalytic activity of sol–gel derived titania converted into nanocrystalline powders by supercritical drying. J Photochem Photobiol A 172 1 1926 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19.

    Deng, C, James, FP, Wright, VP (1998)Poly(tetraethylene glycol malonate)–titanium oxide hybrid materials by sol–gel methods. J Mater Chem 8 1 153159 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20.

    Zheng, M, Gu, M, Jin, Y, Jin, G (2000)Preparation, structure and properties of TiO2–PVP hybrid films. Mater Sci Eng B 77 1 5559 .

  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript submission: www.editorialmanager.com/reac

For subscription options, please visit the website of Springer Nature.

Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
1
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)