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  • 1 Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, China
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Abstract

Ordered Ru-containing mesoporous polymers/silica (xRu-MPS) was for the first time successfully synthesized via a one-pot method. Characterization results demonstrated that the xRu-MPS samples had ordered meso-structure and Ru nanoparticles were highly dispersed on/inside the mesoporous polymer/silica. The xRu-MPS catalysts were proved to be efficient for the hydrogenation of benzaldehyde and its derivatives. When the Ru loading reached up to 4.8 wt%, the conversion of benzaldehyde could arrive 96% with 97% selectivity to benzyl alcohol. The 4.8Ru-MPS catalyst can also catalyze the hydrogenation of a series of benzaldehyde derivatives with different substituents at the phenyl ring with high performance. The results are quite comparable with those obtained on mesopolymer supported Ru catalyst prepared by a traditional impregnation method.

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Manuscript submission: www.editorialmanager.com/reac

  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)