Authors:
Mouheddin Alhaffar Center of Research Excellence in Nanotechnology, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran 31261, Saudi Arabia

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Rami Suleiman Center of Research Excellence in Corrosion, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran 31261, Saudi Arabia

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S. M. Shakil Hussain Chemistry Department, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran 31261, Saudi Arabia

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Bassam El Ali Chemistry Department, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran 31261, Saudi Arabia

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Abstract

Ultranox626 as a diphosphite ligand showed high selectivity and good yields when used with Rh(CO)2(acac) as a catalyst precursor in the hydroformylation of allylbenzene derivatives producing aldehydes, and also in the one-pot hydroformylation–acetalization forming acetals. These reactions proceed smoothly and effectively to produce the linear aldehydes or acetals with high selectivity. The recycling of the rhodium catalyst was carried out after the careful screening and optimization of the reaction conditions in order to maximize the conversion and the selectivity of the reactions.

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
1
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)